Research Article

Synthesis, Characterization, and Electrochemical Study of Tetradentate Ruthenium-Schiff Base Complexes: Dioxygen Activation with a Cytochrome P450 Model Using 1- or 2-Methylimidazole as Axial Bases

Table 5

Number of electrons involved in the electrolyses of Ru(III)-complexes under oxygen atmosphere in presence of 1-methylimidazole.

Determination of number of electrons for waves 𝐸 p c 1 and 𝐸 p c 2

ComplexNumber of electrons 𝐸 p c 1 Number of electrons 𝐸 p c 2

11.500.44
21.600.36
31.500.46