Transient Exciplex Formation Electron Transfer Mechanism
Figure 11
Dependences of (top) and log () (bottom) on for quenching of triplet states of various quinones by methylbenzenes in MeCN (circles) and CH2Cl2 (squares) (according to the experimental data of Hubig and Kochi [14]). Best plots are shown for simulation of the experimental dependence by (3) ( eV) (dash line) and by concatenated mechanism (16) (solid line). Dotted line shows thermodynamic limit for ET.