Oxidation of Tetracaine Hydrochloride by Chloramine-B in Acid Medium: Kinetic Modeling

Table 2

Effect of varying dielectric constant of medium on the reaction rate at [CAB]_o = 2.0 × 10⁻³ mol dm⁻³; [TCH]_o = 2.0 × 10⁻² mol dm⁻³; and [HClO₄] = 0.2 mol dm⁻³; temp = 303 K.

% MeOH (v/v)	𝐷	10^4𝑘^′ (s^−1)
0	76.73	7.95
5	74.50	8.42
10	72.37	9.75
20	67.48	11.4
30	62.71	12.7
40	58.06	15.9