Table of Contents Author Guidelines Submit a Manuscript
Advances in Physical Chemistry
Volume 2015, Article ID 102583, 9 pages
http://dx.doi.org/10.1155/2015/102583
Research Article

Revisiting Oxidative Dehydrogenation of Ethane by W Doping into MoVMn Mixed Oxides at Low Temperature

1SABIC Technology Center, Riyadh 11551, Saudi Arabia
2School of Chemical Engineering, The University of Queensland, St. Lucia, Brisbane, QLD 4072, Australia

Received 9 November 2014; Revised 17 December 2014; Accepted 31 December 2014

Academic Editor: Jinlong Gong

Copyright © 2015 Mohammed H. Al-Hazmi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. Seifzadeh Haghighi, M. R. Rahimpour, S. Raeissi, and O. Dehghani, “Investigation of ethylene production in naphtha thermal cracking plant in presence of steam and carbon dioxide,” Chemical Engineering Journal, vol. 228, pp. 1158–1167, 2013. View at Publisher · View at Google Scholar · View at Scopus
  2. C. A. Gärtner, A. C. vanVeen, and J. A. Lercher, “Oxidative dehydrogenation of ethane: common principles and mechanistic aspects,” ChemCatChem, vol. 5, no. 11, pp. 3196–3217, 2013. View at Publisher · View at Google Scholar · View at Scopus
  3. X. Lin, C. A. Hoel, W. M. H. Sachtler, K. R. Poeppelmeier, and E. Weitz, “Oxidative dehydrogenation (ODH) of ethane with O2 as oxidant on selected transition metal-loaded zeolites,” Journal of Catalysis, vol. 265, no. 1, pp. 54–62, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. M. L. Rodriguez, D. E. Ardissone, E. Heracleous et al., “Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: a theoretical study,” Catalysis Today, vol. 157, no. 1–4, pp. 303–309, 2010. View at Publisher · View at Google Scholar · View at Scopus
  5. A. Machocki and A. Denis, “Simultaneous oxidative coupling of methane and oxidative dehydrogenation of ethane on the Na+ /CaO catalyst,” Chemical Engineering Journal, vol. 90, no. 1-2, pp. 165–172, 2002. View at Publisher · View at Google Scholar
  6. R. Grabowski and J. Słoczyński, “Kinetics of oxidative dehydrogenation of propane and ethane on VOx/SiO2 pure and with potassium additive,” Chemical Engineering and Processing: Process Intensification, vol. 44, no. 10, pp. 1082–1093, 2005. View at Publisher · View at Google Scholar · View at Scopus
  7. M. D. Argyle, K. Chen, A. T. Bell, and E. Iglesia, “Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia,” Journal of Catalysis, vol. 208, no. 1, pp. 139–149, 2002. View at Publisher · View at Google Scholar · View at Scopus
  8. F. Cavani, N. Ballarini, and A. Cericola, “Oxidative dehydrogenation of ethane and propane: how far from commercial implementation?” Catalysis Today, vol. 127, no. 1–4, pp. 113–131, 2007. View at Publisher · View at Google Scholar · View at Scopus
  9. C. Satterfield, Heterogeneous Catalysis in Practice, McGraw-Hill, New York, NY, USA, 1980.
  10. L. Čapek, J. Adam, T. Grygar et al., “Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family,” Applied Catalysis A: General, vol. 342, no. 1-2, pp. 99–106, 2008. View at Publisher · View at Google Scholar · View at Scopus
  11. T. Blasco, A. Galli, J. M. López Nieto, and F. Trifiró, “Oxidative dehydrogenation of ethane and n-butane on VOx/Al2O3 catalysts,” Journal of Catalysis, vol. 169, no. 1, pp. 203–211, 1997. View at Publisher · View at Google Scholar · View at Scopus
  12. G. Tsilomelekis, A. Christodoulakis, and S. Boghosian, “Support effects on structure and activity of molybdenum oxide catalysts for the oxidative dehydrogenation of ethane,” Catalysis Today, vol. 127, no. 1–4, pp. 139–147, 2007. View at Publisher · View at Google Scholar · View at Scopus
  13. C. Liu and U. S. Ozkan, “Effect of chlorine on redox and adsorption characteristics of Mo/Si:Ti catalysts in the oxidative dehydrogenation of ethane,” Journal of Molecular Catalysis A: Chemical, vol. 220, no. 1, pp. 53–65, 2004. View at Publisher · View at Google Scholar · View at Scopus
  14. A. Khodakov, B. Olthof, A. T. Bell, and E. Iglesia, “Structure and catalytic properties of supported vanadium oxides: support effects on oxidative dehydrogenation reactions,” Journal of Catalysis, vol. 181, no. 2, pp. 205–216, 1999. View at Publisher · View at Google Scholar · View at Scopus
  15. A. Corma, J. M. L. Nieto, and N. Paredes, “Influence of the preparation methods of V-Mg-O catalysts on their catalytic properties for the oxidative dehydrogenation of propane,” Journal of Catalysis, vol. 144, no. 2, pp. 425–438, 1993. View at Publisher · View at Google Scholar · View at Scopus
  16. P. Botella, A. Dejoz, J. M. L. Nieto, P. Concepción, and M. I. Vázquez, “Selective oxidative dehydrogenation of ethane over MoVSbO mixed oxide catalysts,” Applied Catalysis A: General, vol. 298, no. 1-2, pp. 16–23, 2006. View at Publisher · View at Google Scholar · View at Scopus
  17. M. V. Martínez-Huerta, X. Gao, H. Tian, I. E. Wachs, J. L. G. Fierro, and M. A. Bañares, “Oxidative dehydrogenation of ethane to ethylene over alumina-supported vanadium oxide catalysts: relationship between molecular structures and chemical reactivity,” Catalysis Today, vol. 118, no. 3-4, pp. 279–287, 2006. View at Publisher · View at Google Scholar · View at Scopus
  18. Z.-S. Chao and E. Ruckenstein, “Noncatalytic and catalytic conversion of ethane over V-Mg oxide catalysts prepared via solid reaction or mesoporous precursors,” Journal of Catalysis, vol. 222, no. 1, pp. 17–31, 2004. View at Google Scholar
  19. R. B. Watson, S. L. Lashbrook, and U. S. Ozkan, “Chlorine modification of Mo/silica-titania mixed-oxide catalysts for the oxidative dehydrogenation of ethane,” Journal of Molecular Catalysis A: Chemical, vol. 208, no. 1-2, pp. 233–244, 2004. View at Publisher · View at Google Scholar · View at Scopus
  20. R. B. Watson and U. S. Ozkan, “Mo loading effects over Mo/Si: Ti catalysts in the oxidative dehydrogenation of ethane,” Journal of Catalysis, vol. 208, no. 1, pp. 124–138, 2002. View at Publisher · View at Google Scholar · View at Scopus
  21. G. Grubert, E. Kondratenko, S. Kolf, M. Baerns, P. Van Geem, and R. Parton, “Fundamental insights into the oxidative dehydrogenation of ethane to ethylene over catalytic materials discovered by an evolutionary approach,” Catalysis Today, vol. 81, no. 3, pp. 337–345, 2003. View at Publisher · View at Google Scholar · View at Scopus
  22. C. Yokoyama, S. S. Bharadwaj, and L. D. Schmidt, “Platinum-tin and platinum-copper catalysts for autothermal oxidative dehydrogenation of ethane to ethylene,” Catalysis Letters, vol. 38, no. 3-4, pp. 181–188, 1996. View at Publisher · View at Google Scholar · View at Scopus
  23. D. W. Flick and M. C. Huff, “Oxidative dehydrogenation of ethane over supported chromium oxide and Pt modified chromium oxide,” Applied Catalysis A: General, vol. 187, no. 1, pp. 13–24, 1999. View at Publisher · View at Google Scholar · View at Scopus
  24. G. D. Claycomb, P. M. A. Sherwood, B. E. Traxel, and K. L. Hohn, “X-ray photoelectron spectroscopic study of the surface state during ethane oxidative dehydrogenation at millisecond contact times,” The Journal of Physical Chemistry C, vol. 111, no. 50, pp. 18724–18730, 2007. View at Publisher · View at Google Scholar · View at Scopus
  25. E. A. de Graaf, G. Rothenberg, P. J. Kooyman, A. Andreini, and A. Bliek, “Pt0.02Sn0.003Mg0.06 on γ-alumina: a stable catalyst for oxidative dehydrogenation of ethane,” Applied Catalysis A: General, vol. 278, no. 2, pp. 187–194, 2005. View at Publisher · View at Google Scholar · View at Scopus
  26. B. Solsona, A. Dejoz, T. Garcia et al., “Molybdenum-vanadium supported on mesoporous alumina catalysts for the oxidative dehydrogenation of ethane,” Catalysis Today, vol. 117, no. 1-3, pp. 228–233, 2006. View at Publisher · View at Google Scholar · View at Scopus
  27. M. Roussel, M. Bouchard, K. Karim, S. Al-Sayari, and E. Bordes-Richard, “MoVO-based catalysts for the oxidation of ethane to ethylene and acetic acid: influence of niobium and/or palladium on physicochemical and catalytic properties,” Applied Catalysis A: General, vol. 308, pp. 62–74, 2006. View at Publisher · View at Google Scholar · View at Scopus
  28. Q. Xie, L. Chen, W. Weng, and H. Wan, “Preparation of MoVTe(Sb)Nb mixed oxide catalysts using a slurry method for selective oxidative dehydrogenation of ethane,” Journal of Molecular Catalysis A: Chemical, vol. 240, no. 1-2, pp. 191–196, 2005. View at Publisher · View at Google Scholar · View at Scopus
  29. D. Linke, D. Wolf, M. Baerns et al., “Catalytic partial oxidation of ethane to acetic acid over Mo1V0.25Nb0.12Pd0.0005Ox: I. Catalyst performance and reaction mechanism,” Journal of Catalysis, vol. 205, no. 1, pp. 16–31, 2002. View at Publisher · View at Google Scholar · View at Scopus
  30. D. Linke, D. Wolf, M. Baerns, S. Zeyß, U. Dingerdissen, and L. Mleczko, “Catalytic partial oxidation of ethane to acetic acid over Mo1V0.25Nb0.12 Pd0.0005Ox: reactor operation,” Chemical Engineering Science, vol. 57, no. 1, pp. 39–51, 2002. View at Publisher · View at Google Scholar · View at Scopus
  31. D. Linke, D. Wolf, M. Baerns, S. Zeyß, and U. Dingerdissen, “Catalytic partial oxidation of ethane to acetic acid over Mo1V0.25Nb0.12Pd0.0005Ox: II. Kinetic modelling,” Journal of Catalysis, vol. 205, no. 1, pp. 32–43, 2002. View at Google Scholar
  32. E. M. Thorsteinson, T. P. Wilson, F. G. Young, and P. H. Kasai, “The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium,” Journal of Catalysis, vol. 52, no. 1, pp. 116–132, 1978. View at Publisher · View at Google Scholar · View at Scopus
  33. X. Lin, K. R. Poeppelmeier, and E. Weitz, “Oxidative dehydrogenation of ethane with oxygen catalyzed by K-Y zeolite supported first-row transition metals,” Applied Catalysis A: General, vol. 381, no. 1-2, pp. 114–120, 2010. View at Publisher · View at Google Scholar · View at Scopus
  34. D. Vitry, Y. Morikawa, J. L. Dubois, and W. Ueda, “Mo-V-Te-(Nb)-O mixed metal oxides prepared by hydrothermal synthesis for catalytic selective oxidations of propane and propene to acrylic acid,” Applied Catalysis A: General, vol. 251, no. 2, pp. 411–424, 2003. View at Publisher · View at Google Scholar · View at Scopus
  35. K. Karim, A. Mamedov, M. H. Al-Hazmi, and N. Al-Andis, “Oxidative dehydrogenation of ethane over MoVMnW oxide catalysts,” Reaction Kinetics and Catalysis Letters, vol. 80, no. 1, pp. 3–11, 2003. View at Publisher · View at Google Scholar · View at Scopus
  36. K. S. Karim, M. H. Al-Hazmi, and N. Al-Andis, “Catalysts for oxidative dehydrogenation of ethane,” Arabian Journal for Science and Engineering, vol. 24, no. 1, pp. 41–48, 1999. View at Google Scholar · View at Scopus
  37. J. Tichý, “Oxidation of acrolein to acrylic acid over vanadium-molybdenum oxide catalysts,” Applied Catalysis A: General, vol. 157, no. 1-2, pp. 363–385, 1997. View at Publisher · View at Google Scholar · View at Scopus
  38. T. Blasco, J. M. L. Nieto, A. Dejoz, and M. I. Vazquez, “Influence of the acid-base character of supported vanadium catalysts on their catalytic properties for the oxidative dehydrogenation of n-butane,” Journal of Catalysis, vol. 157, no. 2, pp. 271–282, 1995. View at Publisher · View at Google Scholar · View at Scopus
  39. A. Dejoz, J. M. López Nieto, F. Márquez, and M. I. Vázquez, “The role of molybdenum in Mo-doped V-Mg-O catalysts during the oxidative dehydrogenation of n-butane,” Applied Catalysis A: General, vol. 180, no. 1-2, pp. 83–94, 1999. View at Publisher · View at Google Scholar · View at Scopus
  40. J. Guan, H. Xu, K. Song et al., “Selective oxidation and oxidative dehydrogenation of isobutane over hydrothermally synthesized Mo-V-O mixed oxide catalysts,” Catalysis Letters, vol. 126, no. 3-4, pp. 293–300, 2008. View at Publisher · View at Google Scholar · View at Scopus
  41. E. R. Stobbe, B. A. de Boer, and J. W. Geus, “The reduction and oxidation behaviour of manganese oxides,” Catalysis Today, vol. 47, no. 1–4, pp. 161–167, 1999. View at Publisher · View at Google Scholar · View at Scopus
  42. B. Solsona, J. M. López Nieto, P. Concepción, A. Dejoz, F. Ivars, and M. I. Vázquez, “Oxidative dehydrogenation of ethane over Ni-W-O mixed metal oxide catalysts,” Journal of Catalysis, vol. 280, no. 1, pp. 28–39, 2011. View at Publisher · View at Google Scholar · View at Scopus
  43. P. Botella, E. García-González, A. Dejoz, J. M. López Nieto, M. I. Vázquez, and J. González-Calbet, “Selective oxidative dehydrogenation of ethane on MoVTeNbO mixed metal oxide catalysts,” Journal of Catalysis, vol. 225, no. 2, pp. 428–438, 2004. View at Publisher · View at Google Scholar · View at Scopus
  44. M. D. Argyle, K. Chen, A. T. Bell, and E. Iglesia, “Ethane oxidative dehydrogenation pathways on vanadium oxide catalysts,” Journal of Physical Chemistry B, vol. 106, no. 21, pp. 5421–5427, 2002. View at Publisher · View at Google Scholar · View at Scopus
  45. S. Al-Khattaf, J. A. Atias, K. Jarosch, and H. de Lasa, “Diffusion and catalytic cracking of 1,3,5 tri-iso-propyl-benzene in FCC catalysts,” Chemical Engineering Science, vol. 57, no. 22-23, pp. 4909–4920, 2002. View at Publisher · View at Google Scholar · View at Scopus
  46. A. Voorhies, “Carbon formation in catalytic cracking,” Industrial & Engineering Chemistry, vol. 37, no. 4, pp. 318–322, 1945. View at Publisher · View at Google Scholar
  47. A. K. Agarwal and M. L. Brisk, “Sequential experimental design for precise parameter estimation. 1. Use of reparameterization,” Industrial & Engineering Chemistry Process Design and Development, vol. 24, pp. 203–207, 1986. View at Google Scholar
  48. Y. Choi and P. Liu, “Mechanism of ethanol synthesis from syngas on Rh(111),” Journal of the American Chemical Society, vol. 131, no. 36, pp. 13054–13061, 2009. View at Publisher · View at Google Scholar · View at Scopus
  49. Y. Choi and P. Liu, “Understanding of ethanol decomposition on Rh(1 1 1) from density functional theory and kinetic Monte Carlo simulations,” Catalysis Today, vol. 165, no. 1, pp. 64–70, 2011. View at Publisher · View at Google Scholar · View at Scopus