Kinetics and Mechanistic Study of Permanganate Oxidation of Fluorenone Hydrazone in Alkaline Medium

Table 1

Effect of variation of [MnO], [FH], [OH], and on the observed first-order rate constants () in the oxidations of fluorenone hydrazone by alkaline permanganate at 25°C.

10^4 [MnO] (mol dm^−3)	10^3 [FH] (mol dm^−3)	10^2 [OH] (mol dm^−3)	(mol dm^−3)	10^4   (s^−1)
1.0	8.0	2.0	0.1	19.8
2.0	8.0	2.0	0.1	20.2
3.0	8.0	2.0	0.1	19.2
4.0	8.0	2.0	0.1	19.6
6.0	8.0	2.0	0.1	18.3
8.0	8.0	2.0	0.1	18.9
4.0	2.0	2.0	0.1	7.3
4.0	4.0	2.0	0.1	12.0
4.0	6.0	2.0	0.1	15.8
4.0	8.0	2.0	0.1	19.6
4.0	10.0	2.0	0.1	22.8
4.0	12.0	2.0	0.1	25.6
4.0	8.0	0.5	0.1	9.8
4.0	8.0	1.0	0.1	14.2
4.0	8.0	1.5	0.1	17.4
4.0	8.0	2.0	0.1	19.6
4.0	8.0	3.0	0.1	23.6
4.0	8.0	4.0	0.1	27.3
4.0	8.0	2.0	0.1	19.6
4.0	8.0	2.0	0.2	18.9
4.0	8.0	2.0	0.3	20.7
4.0	8.0	2.0	0.4	19.2
4.0	8.0	2.0	0.5	18.9
4.0	8.0	2.0	0.6	20.2

Experimental error is ±3%.