Kinetic and Mechanistic Studies on the Reaction of DL-Methionine with [(H₂O)(tap)₂RuORu(tap)₂(H₂O)]²⁺ in Aqueous Medium at Physiological pH

Table 2

10⁵𝑘_2(obs) values for different ligand concentrations at different temperatures. [Complex]=1×10⁻⁴moldm⁻³, pH = 7.4, ionic strength =0.1moldm⁻³NaClO₄.

10^3 [ligand](moldm^−3)	Temperature (^∘C)
	45	50	55	60
2.0	2.27	3.41	5.95	8.93
3.0	2.92	4.5	8.2	11.63
4.0	3.85	5.98	10.0	15.0
5.0	5.13	7.58	12.2	18.2
10.0	7.4	10.52	17.86	25.0