Kinetic and Mechanistic Studies on the Reaction of DL-Methionine with [(H₂O)(tap)₂RuORu(tap)₂(H₂O)]²⁺ in Aqueous Medium at Physiological pH

Table 3

The 𝑘₁,𝐾^𝐸,𝑘₂, and 𝐾^𝐸 values for the interaction of methionine with (1).

Temperature(^∘C)	10^3𝑘1(s^−1)	𝐾^𝐸(dm^3mol^−1s^−1)	10^5𝑘2(s^−1)	𝐾^𝐸(dm^3mol^−1s^−1)
45	3.06	156	18.0	70
50	3.38	179	25.0	78
55	3.70	197	36.0	98
60	4.06	207	48.0	113