International Journal of Inorganic Chemistry / 2009 / Article / Tab 3

Research Letter

Kinetic and Mechanistic Studies on the Reaction of DL-Methionine with [ ( H 2 O ) ( t a p ) 2 R u O R u ( t a p ) 2 ( H 2 O ) ] 2 + in Aqueous Medium at Physiological pH

Table 3

The π‘˜ 1 , 𝐾 ξ…ž 𝐸 , π‘˜ 2 , and 𝐾 𝐸 ξ…ž ξ…ž values for the interaction of methionine with (1).

Temperature ( ∘ C ) 1 0 3 π‘˜ 1 ( s βˆ’ 1 ) 𝐾 ξ…ž 𝐸 ( d m 3 m o l βˆ’ 1 s βˆ’ 1 ) 1 0 5 π‘˜ 2 ( s βˆ’ 1 ) 𝐾 𝐸 ξ…ž ξ…ž ( d m 3 m o l βˆ’ 1 s βˆ’ 1 )

453.0615618.070
503.3817925.078
553.7019736.098
604.0620748.0113

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