Table of Contents
International Journal of Inorganic Chemistry
Volume 2010, Article ID 628639, 5 pages
http://dx.doi.org/10.1155/2010/628639
Research Article

Synthesis of Silver (I) Complexes of Iminoalkyl Functionalised 𝑁 -Heterocyclic Carbenes

1School of Pharmacy and Chemistry, Faculty of Science, Kingston University, Penrhyn Road, Kingston upon Thames, Surrey KT1 2EE, UK
2Department of Chemistry and Biochemistry, University of Sussex, Falmer, Brighton BN1 9QJ, UK

Received 7 January 2010; Accepted 27 March 2010

Academic Editor: W. T. Wong

Copyright © 2010 Neil A. Williams et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. H. M. J. Wang and I. J. B. Lin, “Facile synthesis of silver(I)-carbene complexes. Useful carbene transfer agents,” Organometallics, vol. 17, no. 5, pp. 972–975, 1998. View at Google Scholar · View at Scopus
  2. I. J. B. Lin and C. S. Vasam, “Preparation and application of N-heterocyclic carbene complexes of Ag(I),” Coordination Chemistry Reviews, vol. 251, no. 5-6, pp. 642–670, 2007. View at Publisher · View at Google Scholar · View at Scopus
  3. T. Weskamp, V. P. W. Böhm, and W. A. Herrmann, “N-heterocyclic carbenes: state of the art in transition-metal-complex synthesis,” Journal of Organometallic Chemistry, vol. 600, no. 1-2, pp. 12–22, 2000. View at Google Scholar · View at Scopus
  4. J. C. Garrison and W. J. Youngs, “Ag(I) N-heterocyclic carbene complexes: synthesis, structure, and application,” Chemical Reviews, vol. 105, no. 11, pp. 3978–4008, 2005. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  5. E. A. B. Kantchev, C. J. O'Brien, and M. G. Organ, “Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions—a synthetic chemist's perspective,” Angewandte Chemie International Edition, vol. 46, no. 16, pp. 2768–2813, 2007. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  6. E. Colacino, J. Martinez, and F. Lamaty, “Preparation of NHC-ruthenium complexes and their catalytic activity in metathesis reaction,” Coordination Chemistry Reviews, vol. 251, no. 5-6, pp. 726–764, 2007. View at Publisher · View at Google Scholar · View at Scopus
  7. L. G. Bonnet, R. E. Douthwaite, and B. M. Kariuki, “Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction,” Organometallics, vol. 22, no. 21, pp. 4187–4189, 2003. View at Publisher · View at Google Scholar · View at Scopus
  8. M. C. Perry, X. Cui, M. T. Powell, D.-R. Hou, J. H. Reibenspies, and K. Burgess, “Optically active iridium imidazol-2-ylidene-oxazoline complexes: preparation and use in asymmetric hydrogenation of arylalkenes,” Journal of the American Chemical Society, vol. 125, no. 1, pp. 113–123, 2003. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  9. H. Clavier, L. Coutable, J.-C. Guillemin, and M. Mauduit, “New bidentate alkoxy-NHC ligands for enantioselective copper-catalysed conjugate addition,” Tetrahedron Asymmetry, vol. 16, no. 5, pp. 921–924, 2005. View at Publisher · View at Google Scholar · View at Scopus
  10. D. Martin, S. Kehrli, M. D'Augustin, H. Clavier, M. Mauduit, and A. Alexakis, “Copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted enones. Construction of all-carbon quaternary chiral centers,” Journal of the American Chemical Society, vol. 128, no. 26, pp. 8416–8417, 2006. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  11. M. Merzouk, T. Moore, and N. A. Williams, “Synthesis of chiral iminoalkyl functionalised N-heterocyclic carbenes and their use in asymmetric catalysis,” Tetrahedron Letters, vol. 48, no. 50, pp. 8914–8917, 2007. View at Publisher · View at Google Scholar · View at Scopus
  12. H. Mandai, K. Mandai, M. L. Snapper, and A. H. Hoveyda, “Three-component Ag-catalyzed enantioselective vinylogous mannich and Aza-Diels-Alder reactions with alkyl-substituted aldehydes,” Journal of the American Chemical Society, vol. 130, no. 52, pp. 17961–17969, 2008. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  13. A. A. D. Tulloch, A. A. Danopoulos, S. Winston, S. Kleinhenz, and G. Eastham, “N-functionalised heterocyclic carbcne complexes of silver,” Dalton Transactions, no. 24, pp. 4499–4506, 2000. View at Publisher · View at Google Scholar · View at Scopus
  14. K. S. Coleman, H. T. Chamberlayne, S. Turberville, M. L. H. Green, and A. R. Cowley, “Silver(I) complex of a new imino N-heterocyclic carbene and ligand transfer to palladium(II) and rhodium(I),” Dalton Transactions, no. 14, pp. 2917–2922, 2003. View at Google Scholar · View at Scopus
  15. J. C. Y. Lin, R. T. W. Huang, C. S. Lee, A. Bhattacharyya, W. S. Hwang, and I. J. B. Lin, “Coinage metal N-heterocyclic carbene complexes,” Chemical Reviews, vol. 109, no. 8, pp. 3561–3598, 2009. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  16. L. G. Bonnet, R. E. Douthwaite, and B. M. Kariuki, “Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction,” Organometallics, vol. 22, no. 21, pp. 4187–4189, 2003. View at Publisher · View at Google Scholar
  17. X. Hu, Y. Tang, P. Gantzel, and K. Meyer, “Silver complexes of a novel tripodal N-heterocyclic carbene ligand: evidence for significant metal-carbene π-interaction,” Organometallics, vol. 22, no. 4, pp. 612–614, 2003. View at Publisher · View at Google Scholar