Syntheses and Crystal Structures of Two Transition Metal Complexes (M = Mn and Co) Containing Malonate and Reduced Imino Nitroxide Radicals

Table 3

Selected bond distances (Å) and bond angles (°) for the complex 2.

Mn(1)–O(2)	2.022(3)	N(3)–C(7)	1.468(5)
Mn(1)–N(2)	2.075(4)	C(1)–C(2)	1.379(7)
Mn(1)–N(1)	2.116(3)	O(2)#1–Mn(1)–O(2)	88.88(19)
O(1)–N(3)	1.406(4)	O(2)#1–Mn(1)–N(2)	167.69(15)
O(2)–C(13)	1.251(6)	O(2)–Mn(1)–N(2)	89.92(11)
O(3)–C(13)	1.238(6)	N(2)–Mn(1)–N(2)#1	93.8(2)
N(1)–C(1)	1.312(5)	N(2)–Mn(1)–N(1)#1	100.87(15)
N(1)–C(5)	1.360(5)	O(2)#1–Mn(1)–N(1)	90.13(15)
N(2)–C(6)	1.287(5)	O(2)–Mn(1)–N(1)	91.38(16)
N(2)–C(10)	1.485(5)	N(2)–Mn(1)–N(1)	77.65(15)
N(3)–C(6)	1.367(5)	N(1)#1–Mn(1)–N(1)	177.9(3)

Symmetry transformations used to generate equivalent atoms: no. 1 −𝑥,𝑦,−𝑧.