Insights into DNA Platination within Unusual Structural Settings
Figure 11
Evolution of starting material, intermediates, and products for the reaction of [Pt(15NH3)2I2], I, with R,S-d(CGCGsTGCG), VIIs based on integration of 2D [1H, 15N] HSQC NMR data. Key: blue diamond: cis-[Pt(15NH3)2I2] starting material; red square: cis-[Pt(15NH3)2I(OH2)]+ monoaqua, monoiodo adduct; green triangle: cis-[Pt(15NH3)2I,S]+ monoiodo, monosulphur adduct; violet circle: cis-[Pt(15NH3)2N,S]2+ reaction end product.
