Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain: [M(BPP)_𝟐(TBTA)(H_𝟐O)_𝟐]_𝑛 [M=Mn(𝟏),Co(𝟐)]

Table 1

Crystallographic data and structural refinement summary for complexes 1 and 2.

Compound	1	2
Empirical formula	C34H32Br4MnN4O6	C34H32Br4CoN4O6
Formula weight	967.21	969.19
T (K)	296.15	296.15
Wavelength (Å)	0.71073	0.71073
Crystal system	Triclinic	Triclinic
Space group	P-1	P-1
a (Å)	9.4671 (11)	9.4522 (8)
b (Å)	9.6578 (14)	9.6130 (9)
c (Å)	11.5218 (14)	13.2728 (12)
α (°)	77.576 (2)	105.3150 (10)
β (°)	84.697 (2)	106.8240 (10)
γ (°)	60.649 (2)	118.8890 (10)
V (Å^3)	896.6 (2)	885.58 (14)
Z	1	1
𝐷calc (mg/mm^3)	1.733	1.817
μ (mm^−1)	4.872	5.047
F (000)	446	477
Crystal size (mm)	0.19 × 0.13 × 0.12	0.23 × 0.17 × 0.15
2θ range for data collection (°)	3.62–59.62	3.66–56.74
Index ranges	−13≤ℎ≤13,	−12≤ℎ≤12,
	−13≤𝑘≤13,	−12≤𝑘≤12,
	−16≤𝑙≤16	−17≤𝑙≤17
Reflections collected	13629	12212
Data/restraints/parameters	5103/0/174	4404/0/223
GOF on 𝐹^2	0.982	1.008
𝑅1 indices [I > 2σ(I)]	0.0402	0.0340
𝑤𝑅2 indices (all data)	0.0887	0.0797
Largest diff. peak/hole (eÅ^−3)	0.51/−0.52	0.50/−0.48