Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain: [M(BPP)_𝟐(TBTA)(H_𝟐O)_𝟐]_𝑛 [M=Mn(𝟏),Co(𝟐)]

Table 2

Selected bond lengths (Å) and bond angles (°) for compounds 1 and 2.

1
Bond	Dist.	Bond	Dist.	Bond	Dist.
Mn(1)−O(1)a	2.144(18)	Mn(1)−O(1)	2.1449(18)	Mn(1)−O(3)a	2.1926(8)
Mn(1)−O(3)	2.1926(8)	Mn(1)−N(1)a	2.3087	Mn(1)−N(1)	2.3087
Angle	(°)	Angle	(°)	Angle	(°)
O(1)−Mn(1)−O(1)a	180.0	O(1)−Mn(1)−O(3)	93.13(6)	O(1)a−Mn(1)−O(3)	86.87(6)
O(1)−Mn(1)−O(3)a	86.87(6)	O(1)a−Mn(1)−O(3)a	93.13(6)	O(1)−Mn(1)−N(1)	88.04(6)
O(1)a−Mn(1)−N(1)	91.96(6)	O(1)a−Mn(1)−N(1)a	88. 04(7)	O(1)−Mn(1)−N(1)a	91.96(7)
O(3)a−Mn(1)−O(3)	180.0	O(3)−Mn(1)−N(1)	90.78(3)	O(3)a−Mn(1)−N(1)	89.22(3)
O(3)−Mn(1)−N(1)a	89.22(3)	O(3)a−Mn(1)−N(1)a	90.78(3)	N(1)a−Mn(1)−N(1)	180.00(6)
2
Bond	Dist.	Bond	Dist.	Bond	Dist.
Co(1)−O(3)b	2.120(3)	Co(1)−O(3)	2.120(3)	Co(1)−O(1)b	2.078(2)
Co(1)−O(1)	2.078(2)	Co(1)−N(1)	2.186(4)	Co(1)−N(1)b	2.186(4)
Angle	(°)	Angle	(°)	Angle	(°)
O(3)b−Co(1)−O(3)	180.00(16)	O(3)−Co(1)−N(1)b	90.68(13)	O(3)−Co(1)−N(1)	89.32(13)
O(3)b−Co(1)−N(1)	90.68(13)	O(3)b−Co(1)−N(1)b	89.32(13)	O(2)b−Co(1)−O(3)b	89.24(11)
O(1)−Co(1)−O(3)b	90.76(11)	O(1)b−Co(1)−O(3)b	90.76(11)	O(1)−Co(1)−O(3)b	89.24(11)
O(1)b−Co(1)−O(1)	180.00(18)	O(1)−Co(1)−N(1)	88.26(12)	O(1)b−Co(1)−N(1)b	88.26(12)
O(1)−Co(1)−N(1)b	91.74(12)	O(1)b−Co(1)−N(1)	91.74(12)	N(1)b−Co(1)−N(1)	180.000(1)

Symmetry transformation: a: −x, z − y, −z; b: 1−𝑥, −y, −z.