Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain: [M(BPP)_𝟐(TBTA)(H_𝟐O)_𝟐]_𝑛 [M=Mn(𝟏),Co(𝟐)]

Table 3

Hydrogen-bond lengths (Å) and bond angles (°) for compounds 1 and 2.

D–H···A	d(D–H)	d(H⋯A)	d(D⋯A)	∠DHA
1
O(3)–H(3A)⋯O(2)^a	0.852	2.669	2.678	81.38
C(15)–H(15)⋯O(2)^b	0.930	2.604	3.337	136.10
C(12)–H(12B)⋯O(2)^c	0.970	2.839	3.752	157.02
2
O(3)–H(3A)⋯O(2)	0.850	3.023	2.675	56.95
O(3)–H(3B)⋯N(2)^d	0.850	2.028	2.774	145.90
C(12)–H(12A)⋯O(2)^e	0.970	2.805	3.729	159.52

Symmetry codes: (a) −x, 2−𝑦, −z; (b) 1−𝑥, 1−𝑦, 1−𝑧; (c) x, 𝑦−1, z; (d) x, y, 𝑧−1; (e) 𝑥−1, 𝑦−1, z.