Table of Contents
International Journal of Inorganic Chemistry
Volume 2012, Article ID 515196, 6 pages
http://dx.doi.org/10.1155/2012/515196
Research Article

Reversed-Phase Column Extractive Separation of Gd(III) with Poly[dibenzo-18-crown-6]

1Analytical and Environmental Research Lab, Department of Chemistry, Shivaji University, Kolhapur 416 004, India
2Department of Chemistry, Jaysingpur College, Jaysingpur 416101, India

Received 12 November 2011; Accepted 6 February 2012

Academic Editor: Karl Kirchner

Copyright © 2012 K. R. Mahanwar et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. P. Maestro and D. Huguenin, “Industrial applications of rare earths: which way for the end of the century,” Journal of Alloys and Compounds, vol. 225, no. 1-2, pp. 520–528, 1995. View at Google Scholar · View at Scopus
  2. J. Will, A. Mitterdorfer, C. Kleinlogel, D. Perednis, and L. J. Gauckler, “Fabrication of thin electrolytes for second-generation solid oxide fuel cells,” Journal of Solid State Ionics, vol. 131, no. 1, pp. 79–96, 2000. View at Publisher · View at Google Scholar · View at Scopus
  3. C. Kantipuly, S. Katragadda, A. Chow, and H. D. Gesser, “Chelating polymers and related supports for separation and preconcentration of trace metals,” Talanta, vol. 37, no. 5, pp. 491–517, 1990. View at Google Scholar · View at Scopus
  4. C. J. Kantipuly and A. D. Westland, “Review of methods for the determination of lanthanides in geological samples,” Talanta, vol. 35, no. 1, pp. 1–13, 1988. View at Google Scholar · View at Scopus
  5. G. V. Mgasoedova and S. B. Savvin, “Chelating sorbents in analytical chemistry,” Critical Reviews in Analytical Chemistry, vol. 17, no. 1, pp. 1–63, 1986. View at Publisher · View at Google Scholar
  6. A. Warshawsky, “Selective ion exchange polymers,” Die Angewandte Makromolekulare Chemie, vol. 109, no. 1, pp. 171–196, 1982. View at Publisher · View at Google Scholar
  7. J. L. Cortina and A. Warshawsky, “Developments in solid-liquid extraction by solvent impregnated resins,” in Ion Exchange and Solvent Extraction, J. A. Marinsky and Y. Marcus, Eds., vol. 13, p. 195, Marcel Dekker, New York, NY, USA, 1997. View at Google Scholar
  8. A. Naim, Z. Hans, and M. B. Harry, “Strontium ion selective electrode based on a conducting poly(Dibenzo-18-Crown-6) film,” Analytical Letters, vol. 24, no. 8, pp. 1431–1443, 1991. View at Publisher · View at Google Scholar
  9. L. Angely, V. Questaigne, and J. Rault-Berthelot, “The influence of poly-dibenzo-crown ether treatments on their complexing properties: application to Ag+ extraction,” Synthetic Metals, vol. 52, no. 1, pp. 111–124, 1992. View at Google Scholar · View at Scopus
  10. M. R. Shivade and V. M. Shinde, “Extraction of gadolinium with liquid ion-exchangers,” Fresenius' Zeitschrift für Analytische Chemie, vol. 317, no. 7, p. 792, 1984. View at Publisher · View at Google Scholar · View at Scopus
  11. N. de Jong, M. Draye, A. Favre-Réguillon, G. LeBuzit, G. Cote, and J. Foos, “Lanthanum(III) and gadolinium(III) separation by cloud point extraction,” Journal of Colloid and Interface Science, vol. 291, no. 1, pp. 303–306, 2005. View at Publisher · View at Google Scholar · View at Scopus
  12. J. E. Powell and H. R. Burkholder, “Augmenting the separation of gadolinium and europim and europium and samarium mixtures in ion exchange elutions with EDTA,” Journal of Chromatography A, vol. 29, pp. 210–217, 1967. View at Google Scholar · View at Scopus
  13. C. A. Morais and V. S. T. Ciminelli, “Selection of solvent extraction reagent for the separation of europium(III) and gadolinium(III),” Minerals Engineering, vol. 20, no. 8, pp. 747–752, 2007. View at Publisher · View at Google Scholar · View at Scopus
  14. D. Nayak and S. Lahiri, “Extraction and separation of141Ce and153Gd with HDEHP,” Journal of Radioanalytical and Nuclear Chemistry, vol. 240, no. 1, pp. 75–77, 1999. View at Google Scholar · View at Scopus
  15. B. S. Mohite, C. D. Jadage, and S. R. Pratap, “Method for the extraction chromatographic separation of barium from other elements with dibenzo-18-crown-6,” Analyst, vol. 115, no. 10, pp. 1367–1369, 1990. View at Google Scholar · View at Scopus
  16. N. Y. Kremliakova, A. P. Novikov, and B. F. Myasoedov, “Extraction chromatographic separation of radionuclides of strontium, cesium and barium with the use of TVEX-DCH18C6,” Journal of Radioanalytical and Nuclear Chemistry, vol. 145, no. 1, pp. 23–28, 1990. View at Publisher · View at Google Scholar · View at Scopus
  17. E. P. Horwitz, M. L. Dietz, and D. E. Fisher, “Separation and preconcentration of strontium from biological, environmental, and nuclear waste samples by extraction chromatography using a crown ether,” Analytical Chemistry, vol. 63, no. 5, pp. 522–525, 1991. View at Google Scholar
  18. B. S. Mohite and A. S. Jadhav, “Column chromatographic separation of uranium(VI) and other elements using poly(dibenzo-18-crown-6) and ascorbic acid medium,” Journal of Chromatography A, vol. 983, no. 1-2, pp. 277–281, 2003. View at Publisher · View at Google Scholar · View at Scopus
  19. B. S. Mohite and A. S. Jadhav, “Column chromatographic separation of thorium(IV) from ascorbic acid medium using poly-(dibenzo-18-crown-6),” Journal of Radioanalytical and Nuclear Chemistry, vol. 256, no. 1, pp. 173–176, 2003. View at Publisher · View at Google Scholar · View at Scopus
  20. B. S. Mohite, J. M. Patil, and D. N. Zambare, “Column chromatographic separation of molybdenum (VI) from alloys with poly-(dibenzo-18-crown-6) from a hydrochloric acid medium,” Talanta, vol. 40, no. 10, pp. 1511–1518, 1993. View at Google Scholar · View at Scopus
  21. B. S. Mohlte, D. N. Zambare, and B. E. Mahadik, “Potassium Separation from S-Block and Other Elements Using a Polymeric Crown Ether,” Analytical Chemistry, vol. 66, no. 22, pp. 4097–4099, 1994. View at Google Scholar · View at Scopus
  22. B. S. Mohite, J. M. Patil, and D. N. Zambare, “Solvent extraction separation of uranium(VI) with dibenzo-24-crown-8,” Journal of Radioanalytical and Nuclear Chemistry, vol. 170, no. 1, pp. 215–224, 1993. View at Publisher · View at Google Scholar · View at Scopus
  23. S. R. Sabale, D. V. Jadhav, and B. S. Mohite, “Sorption study of U(VI), Th(IV) and Ce(III) on poly[dibenzo-18-crown-6] in l-arginine to develop sequential column chromatographic separation method,” Journal of Radioanalytical and Nuclear Chemistry, vol. 284, no. 2, pp. 273–278, 2010. View at Publisher · View at Google Scholar · View at Scopus
  24. A. I. Vogel, A Textbook of Quantitative Inorganic Analysis, Longmans, London, UK, 3rd edition, 1975.
  25. Z. Marczenko, Spectrophotometer Determination of Elements, Ellis Horword Limited, Chichester, UK, 1976.
  26. V. P. Dedkova, O. P. Shvoeva, and S. B. Savvin, “Sorption-spectrometric determination of thorium(IV) and uranium(VI) with the reagent Arsenazo III on the solid phase of a fibrous material filled with a cation exchanger,” Journal of Analytical Chemistry, vol. 63, no. 5, pp. 430–434, 2008. View at Publisher · View at Google Scholar · View at Scopus