Table of Contents
International Journal of Inorganic Chemistry
Volume 2013, Article ID 524179, 6 pages
http://dx.doi.org/10.1155/2013/524179
Research Article

Syntheses and Characterization of the Coordination Compounds of N-(2-hydroxymethylphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one

1Department of Chemistry, National Institute of Technology, Haryana, Kurukshetra 136119, India
2Department of Chemistry, Haryana College of Technology & Management, Haryana, Kaithal 136027, India
3Department of Chemistry, Shri Krishan Institute of Engineering & Technology, Haryana, Kurukshetra 136118, India

Received 26 December 2012; Accepted 7 February 2013

Academic Editor: Hakan Arslan

Copyright © 2013 Dinesh Kumar et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A dry benzene solution of the Schiff base N-(2-hydroxymethylphenyl)-3′-carboxy-2′-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxymethylphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with Co(II), Ni(II), Cd(II), Zr(OH)2(IV), and UO2(VI) ions and forms the monomeric coordination compounds, [M(LH)(MeOH)3] [where M = Co(II), Ni(II)], [M′(LH)(MeOH)] [here M′ = Cd(II), UO2(VI)] and [Zr(OH)2(LH)(MeOH)]. The coordination compounds have been characterized on the bases of elemental analyses, molar conductance, molecular weight, spectral (IR, NMR, and reflectance) studies, and magnetic susceptibility measurements. I behaves as a dibasic tridentate OOS donor ligand in these compounds. The compounds are nonelectrolytes ( = 3.8–8.9 mho cm2 mol−1) in DMF. A tetrahedral structure for [Cd(LH)(MeOH)] and an octahedral structure for the remaining compounds are suggested.