Nickel (II) and Iron (II) Complexes with Azole Derivatives: Synthesis, Crystal Structures and Antifungal Activities

Table 2

Selected bond lengths (Å) and bond angles (°) of 1 and 2.

Complex ( 𝟏 )
Ni(1)-O(1)	2.109(6)	O(1)-Ni(1)-N(1)	89.8(3)
Ni(1)-N(1)	2.105(8)	O(1)-Ni(1)-N(2)	90.4(3)
Ni(1)-N(2)	2.309(7)	O(1)-Ni(1)-O(1)	180.0(2)
		N(1)-Ni(1)-N(1)	180.0(3)
		N(1)-Ni(1)-N(2)	100.8(3)
		N(2)-Ni(1)-N(2)	180.0(3)
Complex (2)
Fe(1)-N(2)	2.133(2)	N(2)-Fe(1)-N(1)	73.66(8)
Fe(1)-N(4)	2.107(3)	N(1)-Fe(1)-N(2)	96.87(9)
Fe(1)-N(1)	2.250(2)	N(2)-Fe(1)-N(4)	87.61(1)
N(4)-C(008)	1.159(4)	N(4)-Fe(1)-N(4)	99.90(1)
S(2)-C(008)	1.618(4)	N(4)-Fe(1)-N(1)	90.90(1)
N(2)-N(3)	1.351(3)	N(4)-Fe(1)-N(2)	87.60(1)

Symmetry transformations used to generate equivalent atoms for ( 𝟏 ): 𝑥, 𝑦, 𝑧, 1/2 −z, −𝑥, −𝑦, −𝑧, 1/2 +x, 1/2 −y, 1/2 +z. (2): −𝑥, 𝑦, 1/2 −z, 1/2 +y, 𝑧, 1/2 −x, 𝑥, −𝑦, −𝑧, 1/2 +z, 1/2 −y.