Research Article

Characterization of Complexes Synthesized Using Schiff Base Ligands and Their Screening for Toxicity Two Fungal and One Bacterial Species on Rice Pathogens

Table 1

Elemental composition and physical data of BHFH ligand and its complexes.

S. number Complex Mpt
°C
ColourCHNMClMol Wt
gm
Remarks
Observed (calculated) %

1BHFH-L1
(C12H8N2O3)
210White63.00
(63.18)
4.50
(4.38)
12.56
(12.27)
228.13Loss of 2H

2[Cu(BHFH)]2-pH 5.5–7.0
Cu2C24H16N4O6
308Grey50.02
(50.10)
2.90
(2.78)
10.00
(9.73)
20.95
(22.09)
575.35Loss of 8H

3[Cu(BHFH)H2O]-pH 8.5
CuC12H10N2O4
280Green47.20
(47.44)
3.45
(3.29)
9.50
(9.22)
20.00
(20.94)
303.55Loss of 8H

4[Ni(BHFH)H2O]-pH 5.5–7.0
NiC12H10N2O4
265Red50.00
(50.25)
3.50
(3.49)
9.20
(9.76)
20.00
(20.47)
286.83Loss of H2O

5[Ni(BHFH)2]-pH 8.5
NiC24H16N4O6
280Green56.00
(56.17)
4.00
(3.90)
11.00
(10.92)
11.50
(11.45)
512.70Loss of 6H

6[Co(BHFH)(H2O)Cl]2
Co2C24H20N4O8Cl2
260Pink42.55
(42.70)
3.30
(3.26)
8.51
(8.29)
17.50
(17.46)
10.50
(10.52)
675.12Loss of 8H

7 [Fe(BHFH)Cl2]2
Fe2C24H16N4O8Cl4
320Red40.50
(40.58)
2.80
(2.82)
7.92
(7.89)
16.00
(15.74)
20.00
(20.01)
709.70Loss of 4H

8[Mn(BHFH)(H2O)Cl]2
Mn2C24H20N4O8Cl2
280Yellow44.50
(44.65)
2.98
(3.10)
8.12
(8.68)
17.00
(16.90)
10.00
(11.01)
645.00Loss of 1.5H2O

9[VO(BHFH)Cl]2
V2C24H16N4O8Cl2
285Grey44.00
(44.14)
3.00
(3.06)
8.50
(8.57)
15.00
(15.60)
10.74
(10.87)
653.14Loss of 8H