International Journal of Inorganic Chemistry / 2014 / Article / Tab 1 / Research Article
Characterization of Complexes Synthesized Using Schiff Base Ligands and Their Screening for Toxicity Two Fungal and One Bacterial Species on Rice Pathogens Table 1 Elemental composition and physical data of BHFH ligand and its complexes.
S. number
Complex
Mpt °C Colour C H N M Cl Mol Wt gm
Remarks Observed (calculated) % 1 BHFH-L1 (C12 H8 N2 O3 ) 210 White 63.00 (63.18) 4.50 (4.38) 12.56 (12.27) — — 228.13 Loss of 2H 2 [Cu(BHFH)]2 -pH 5.5–7.0 Cu2 C24 H16 N4 O6 308 Grey 50.02 (50.10) 2.90 (2.78) 10.00 (9.73) 20.95 (22.09) — 575.35 Loss of 8H 3 [Cu(BHFH)H2 O]-pH 8.5 CuC12 H10 N2 O4 280 Green 47.20 (47.44) 3.45 (3.29) 9.50 (9.22) 20.00 (20.94) — 303.55 Loss of 8H 4 [Ni(BHFH)H2 O]-pH 5.5–7.0 NiC12 H10 N2 O4 265 Red 50.00 (50.25) 3.50 (3.49) 9.20 (9.76) 20.00 (20.47) — 286.83 Loss of H2 O 5 [Ni(BHFH)2 ]-pH 8.5 NiC24 H16 N4 O6 280 Green 56.00 (56.17) 4.00 (3.90) 11.00 (10.92) 11.50 (11.45) — 512.70 Loss of 6H 6 [Co(BHFH)(H2 O)Cl]2 Co2 C24 H20 N4 O8 Cl2 260 Pink 42.55 (42.70) 3.30 (3.26) 8.51 (8.29) 17.50 (17.46) 10.50 (10.52) 675.12 Loss of 8H 7
[Fe(BHFH)Cl2 ]2 Fe2 C24 H16 N4 O8 Cl4 320 Red 40.50 (40.58) 2.80 (2.82) 7.92 (7.89) 16.00 (15.74) 20.00 (20.01) 709.70 Loss of 4H 8 [Mn(BHFH)(H2 O)Cl]2 Mn2 C24 H20 N4 O8 Cl2 280 Yellow 44.50 (44.65) 2.98 (3.10) 8.12 (8.68) 17.00 (16.90) 10.00 (11.01) 645.00 Loss of 1.5H2 O 9 [VO(BHFH)Cl]2 V2 C24 H16 N4 O8 Cl2 285 Grey 44.00 (44.14) 3.00 (3.06) 8.50 (8.57) 15.00 (15.60) 10.74 (10.87) 653.14 Loss of 8H