Table of Contents
International Journal of Inorganic Chemistry
Volume 2014, Article ID 768575, 4 pages
http://dx.doi.org/10.1155/2014/768575
Research Article

Kinetics and Mechanism of the Oxidation of Naphthol Green B by Peroxydisulphate Ion in Aqueous Acidic Medium

1Department of Basic Research, National Research Institute for Chemical Technology, PMB 1052, Zaria, Kaduna State, Nigeria
2Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria

Received 21 October 2013; Revised 21 February 2014; Accepted 24 February 2014; Published 25 March 2014

Academic Editor: Alfonso Castiñeiras

Copyright © 2014 B. Myek et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. Edward, Synthesis Dyes in Biology, Medicine and Chemistry, Academic Press, London, UK, 1971.
  2. B. Myek, S. O. Idris, and J. F. Iyun, “Kinetics of the oxidation of naphthol green B by periodate ion in aqueous hydrochloric acid medium,” International Journal of Modern Chemistry, vol. 5, no. 2, pp. 127–135, 2013. View at Google Scholar
  3. Y. Liu and P. Wang, “Kinetic spectrophotometric method for the determination of cerium(IV) with naphthol green B,” Rare Metals, vol. 28, no. 1, pp. 5–8, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. J. W. L. Fordham and H. Leverne Williams, “The persulfate-iron(II) initiator system for free radical polymerizations,” Journal of The American Chemical Society, vol. 73, no. 10, pp. 4855–4859, 1951. View at Google Scholar · View at Scopus
  5. D. H. Irvine, “441. The oxidation of the trisdipyridylosmium(II) ion by the peroxydisulphate ion in aqueous solution,” Journal of the Chemical Society (Resumed), pp. 2166–2170, 1958. View at Publisher · View at Google Scholar · View at Scopus
  6. D. M. Yost and H. H. Clausen, “Reduction of peroxysulfate by vanadyl ion with silver ion as catalyst,” Journal of the American Chemical Society, vol. 53, no. 9, pp. 3349–3354, 1931. View at Google Scholar · View at Scopus
  7. K. Y. Gupta and D. D. Misra, “The silver ion catalyses oxidation of arsenous acid by S2O82-,” Bulletin of the Chemical Society of Japan, vol. 32, pp. 1306–1309, 1959. View at Google Scholar
  8. R. W. Chlebeck and N. W. Lister, “Reaction between alkali metal ferrocyanides and peroxydisulphate in aqueous,” Canadian Journal of Chemistry, vol. 45, pp. 2411–2418, 1967. View at Google Scholar
  9. S. Raman and J. H. C. Brubakar, “The kinetics of the oxidation of substituted 2, 2′-bipyridine and 1, 10-phenanthroline complexes of iron (II), with S2O82- ion,” Journal of Inorganic and Nuclear Chemistry, vol. 31, pp. 1091–1201, 1969. View at Google Scholar
  10. S. S. Gupta and Y. K. Gupta, “Kinetics and mechanism of the iron(III)-catalyzed oxidation of hydrazine with peroxydisulfate in acid medium,” Inorganic Chemistry, vol. 20, no. 6, pp. 1748–1751, 1981. View at Google Scholar · View at Scopus
  11. D. E. Pennington and A. Haim, “Kinetics and mechanism of the chromium(II)-catalyzed substitution of iodide ion in the iodopentaaquochromium(III) ion by water and by fluoride, chloride, and bromide ions,” Inorganic Chemistry, vol. 6, no. 12, pp. 2138–2146, 1967. View at Google Scholar · View at Scopus
  12. K. Ohashi, H. E. Matsuzama, and Yamamato, “The kinetics study of the oxidation reaction of tris-(2, 2′-bypyridine)Cobalt (II) ion and ethylenediamine-N, N, N′, N’tetraacetate(II) ion by S2O82-,” Bulletin of the Chemical Society of Japan, vol. 49, no. 9, pp. 2440–2442, 1976. View at Google Scholar
  13. G. A. Ayoko, J. F. Iyun, and I. F. El-Idris, “Electron transfer at tetrahedral cobalt(II), part III: kinetics of copper(II) ion catalysed reduction of periodate,” Transition Metal Chemistry, vol. 17, no. 5, pp. 423–425, 1992. View at Publisher · View at Google Scholar · View at Scopus
  14. K. Y. Gupta and S. Ghosh, “Hydrogen ion dependence of the oxidation of iron(II) with peroxydisulphate in acidic perchlorate solutions,” Inorganic Chemistry, vol. 20, pp. 434–439, 1959. View at Google Scholar
  15. Y. Mohammed, J. F. Iyun, and S. O. Idris, “Kinetic approach to the mechanism of the redox reaction of malachite green and permanganate ion in aqueous acidic medium,” African Journal of Pure and Applied Chemistry, vol. 3, no. 12, pp. 269–274, 2009. View at Google Scholar
  16. G. Adefikayo Ayoko, J. Femi Iyun, and I. Faskari El-Idris, “Electron transfer at tetrahedral cobalt(II), part II. Kinetics of silver(I) ion catalyzed reduction of peroxydisulphate,” Transition Metal Chemistry, vol. 17, pp. 46–49, 1992. View at Google Scholar
  17. S. S. Gupta and Y. K. Gupta, “Hydrogen ion dependence of the oxidation of iron(II) with peroxydisulphate in acidic perchlorate solutions,” Inorganic Chemistry, vol. 20, pp. 434–439, 1981. View at Google Scholar
  18. P. Banerjee and P. M. Pujara, “The kinetics of oxidation of N(2-hydroxyl)ethylenediamminetetraacetatecobaltate(II) by S2O82- in aqueous acidic solution,” Transition Metal Chemistry, vol. 6, pp. 47–54, 1981. View at Google Scholar
  19. P. S. V. Rao, P. S. N. Murty, and L. A. N. Murty, “Kinetic and mechanism of indigo carmine with peroxydisulphate,” Journal of the Chemical Society, vol. 60, p. 1180, 1978. View at Google Scholar
  20. T. J. Mayer and H. Taube, Comprehensive Coordination Chemistry: The Synthesis, Reaction, Properties and Application of Coordination Compounds, Pergamon Press, London, UK, 1987.