Table of Contents
International Journal of Inorganic Chemistry
Volume 2015, Article ID 106838, 8 pages
http://dx.doi.org/10.1155/2015/106838
Research Article

Synthesis, Crystal Structure, and Antimicrobial Properties of a Novel 1-D Cobalt Coordination Polymer with Dicyanamide and 2-Aminopyridine

1Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, P.O. Box 812, Yaoundé, Cameroon
2Department of Chemistry, Faculty of Science, The University of Bamenda, P.O. Box 39, Bambili, Bamenda, Cameroon
3Département de Chimie, Faculté des Sciences, Université de Douala, Douala, Cameroon
4Sophisticated Analytical Instruments Facility, Indian Institute of Technology, Madras, Chennai 600036, India
5Department of Organic Chemistry, Faculty of Science, University of Yaoundé I, P.O. Box 812, Yaoundé, Cameroon

Received 6 April 2015; Revised 4 June 2015; Accepted 7 June 2015

Academic Editor: Alfonso Castiñeiras

Copyright © 2015 Amah Colette Benedicta Yuoh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A novel one-dimensional coordination polymer bis(2-aminopyridine)-μ-bis(dicyanamido) cobaltate(II) has been synthesized and characterized by elemental analyses and infrared and ultraviolet visible spectroscopies and the structure has been determined by single crystal X-ray diffraction. Co(II) ion in the complex is coordinated to two axial 2-aminopyridine ligands through the pyridine N-atom and four equatorial dicyanamide ligands to give a CoN6 slightly distorted octahedral coordination environment around the metal ion. The amino N-atom forms intrachain hydrogen bonds. Antimicrobial screening of the complex against eight pathogenic microorganisms (four bacteria and four fungi) isolated from humans, indicates that the complex is moderately active.