Table of Contents
International Journal of Inorganic Chemistry
Volume 2016 (2016), Article ID 7095624, 5 pages
http://dx.doi.org/10.1155/2016/7095624
Research Article

Structural Prediction of Bis(di-p-anisole)-1,4-azabutadiene-bis[triphenylphosphine]ruthenium(II) Using 31P NMR Spectroscopy

Department of Chemistry, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak, 94300 Kota Samarahan, Sarawak, Malaysia

Received 22 March 2016; Accepted 1 September 2016

Academic Editor: Alfonso Castiñeiras

Copyright © 2016 Meng Guan Tay et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The present paper reports the use of 31P NMR spectroscopy to predict the isomer structures of [bis4-methoxy-phenyl-[3-(4-methoxy-phenyl)-allylidene]-amino]-bis[triphenylphosphine]ruthenium(II), also known as bis(di-p-anisole)-1,4-azabutadiene-bis[triphenylphosphine]ruthenium(II), complexes. The complexation reaction was carried out under refluxing condition of (di-p-anisole)-1,4-azabutadiene (compound 1), triphenylphosphine (PPh3), and ruthenium chloride in the ratio of 2 : 2 : 1 for five hours. In addition, ruthenium(II) complexes were also characterized using FTIR and UV-Vis spectroscopy to support the formation of ruthenium(II) complexes. 31P NMR spectroscopic study on ruthenium(II) complexes suggested that there are three isomers present after the complexation reaction and all the ruthenium complexes demonstrate octahedral geometry.