Table of Contents
Indian Journal of Materials Science
Volume 2013 (2013), Article ID 718304, 7 pages
http://dx.doi.org/10.1155/2013/718304
Research Article

Electrical Conductivity Studies of Polyaniline Nanotubes Doped with Different Sulfonic Acids

Laboratório de Filmes Finos e Superfícies, Departamento de Fisica, Universidade Federal de Santa Catarina, 88040-900 Florianopolis, Brazil

Received 15 October 2013; Accepted 10 November 2013

Academic Editors: S. K. Dhara, S. K. Kulshreshtha, and V. Privman

Copyright © 2013 Mohd. Khalid et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. D. Li, J. X. Huang, and R. B. Kaner, “Polyaniline nanofibers: a unique polymer nanostructure for versatile applications,” Accounts of Chemical Research, vol. 42, pp. 135–145, 2009. View at Publisher · View at Google Scholar
  2. M. Khalid, J. J. S. Acuña, M. A. Tumelero, J. A. Fischer, V. Zoldan, and A. A. Pasa, “Sulfonated porphyrin doped polyaniline nanotubes and nanofibers: synthesis and characterization,” Journal of Materials Chemistry, vol. 22, pp. 11340–11346, 2012. View at Publisher · View at Google Scholar
  3. M. Khalid and F. Mohammad, “Preparation, FTIR spectroscopic characterization and isothermal stability of differently doped fibrous conducting polymers based on polyaniline and nylon-6,6,” Synthetic Metals, vol. 159, pp. 119–122, 2009. View at Publisher · View at Google Scholar
  4. A. A. Khan and M. Khalid, “Preparation, FTIR spectroscopic characterization and isothermal stability of differently doped conductive fibers based on polyaniline and polyacrylonitrile,” Synthetic Metals, vol. 160, no. 7-8, pp. 708–712, 2010. View at Publisher · View at Google Scholar · View at Scopus
  5. L. Zhang, H. Peng, J. Sui, P. A. Kilmartin, and J. Travas-Sejdic, “Polyaniline nanotubes doped with polymeric acids,” Current Applied Physics, vol. 8, no. 3-4, pp. 312–315, 2008. View at Publisher · View at Google Scholar · View at Scopus
  6. Q. Yao, L. D. Chen, W. Q. Zhang, S. C. Liufu, and X. H. Chen, “Enhanced thermoelectric performance of single-walled carbon nanotubes/polyaniline hybrid nanocomposites,” ACS Nano, vol. 4, no. 4, pp. 2445–2451, 2010. View at Publisher · View at Google Scholar · View at Scopus
  7. R. Sainz, W. R. Small, N. A. Young et al., “Synthesis and properties of optically active polyaniline carbon nanotube composites,” Macromolecules, vol. 39, no. 21, pp. 7324–7332, 2006. View at Publisher · View at Google Scholar · View at Scopus
  8. X. T. Zhang, W. H. Song, P. J. F. Harris, G. R. Mitchell, T. T. T. Bui, and A. F. Drake, “Chiral polymer-carbon-nanotube composite nanofibers,” Advanced Materials, vol. 19, no. 8, pp. 1079–1083, 2007. View at Publisher · View at Google Scholar · View at Scopus
  9. Y. Zhou, Z.-Y. Qin, L. Li et al., “Polyaniline/multi-walled carbon nanotube composites with core-shell structures as supercapacitor electrode materials,” Electrochimica Acta, vol. 55, no. 12, pp. 3904–3908, 2010. View at Publisher · View at Google Scholar · View at Scopus
  10. G. M. Spinks, V. Mottaghitalab, M. Bahrami-Samani, P. G. Whitten, and G. G. Wallace, “Carbon-nanotube-reinforced polyaniline fibers for high-strength artificial muscles,” Advanced Materials, vol. 18, no. 5, pp. 637–640, 2006. View at Publisher · View at Google Scholar · View at Scopus
  11. A. L. Cabezas, Z. B. Zhang, L. R. Zheng, and S. L. Zhang, “Morphological development of nanofibrillar composites of polyaniline and carbon nanotubes,” Synthetic Metals, vol. 160, pp. 664–668, 2010. View at Publisher · View at Google Scholar
  12. J.-Q. Dong and Q. J. Shen, “Enhancement in solubility and conductivity of polyaniline with lignosulfonate modified carbon nanotube,” Journal of Polymer Science B, vol. 47, no. 20, pp. 2036–2046, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. P. Jimenez, W. K. Maser, P. Castell, M. T. Martínez, and A. M. Benito, “Nanofibrilar polyaniline: direct route to Carbon nanotube water dispersions of high concentration,” Macromolecular Rapid Communications, vol. 30, pp. 418–422, 2009. View at Publisher · View at Google Scholar
  14. P. Jimenez, P. Castell, R. Sainz et al., “Carbon nanotube effect on polyaniline morphology in water dispersible composites,” The Journal of Physical Chemistry B, vol. 114, pp. 1579–1585, 2010. View at Publisher · View at Google Scholar
  15. R. Sainz, A. M. Benito, M. T. Martínez et al., “Soluble self-aligned carbon nanotube/polyaniline composites,” Advanced Materials, vol. 17, no. 3, pp. 278–281, 2005. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Ginic-Markovic, J. G. Matisons, R. Cervini, G. P. Simon, and P. M. Fredericks, “Synthesis of new polyaniline/nanotube composites using ultrasonically initiated emulsion polymerization,” Chemistry of Materials, vol. 18, no. 26, pp. 6258–6265, 2006. View at Publisher · View at Google Scholar · View at Scopus
  17. D. Normile, “Nanotubes generate full-color displays,” Science, vol. 286, no. 5447, pp. 2056–2057, 1999. View at Google Scholar · View at Scopus
  18. J. Kong, N. R. Franklin, C. W. Zhou et al., “Nanotube molecular wires as chemical sensors,” Science, vol. 287, no. 5453, pp. 622–625, 2000. View at Publisher · View at Google Scholar · View at Scopus
  19. C. R. Martin, “Nanomaterials: a membrane-based synthetic approach,” Science, vol. 266, no. 5193, pp. 1961–1966, 1994. View at Google Scholar · View at Scopus
  20. J. Huang and M. X. Wan, “In situ doping polymerization of polyaniline microtubules in the presence of β-naphthalenesulfonic acid,” Journal of Polymer Science A, vol. 37, no. 2, pp. 151–157, 1999. View at Google Scholar · View at Scopus
  21. L. Zhang, H. Peng, P. A. Kilmartin, C. Soeller, and J. Travas-Sejdic, “Polymeric acid doped polyaniline nanotubes for oligonucleotide sensors,” Electroanalysis, vol. 19, no. 7-8, pp. 870–875, 2007. View at Publisher · View at Google Scholar · View at Scopus
  22. Z. Zhang, Z. Wei, and M. Wan, “Nanostructures of polyaniline doped with inorganic acids,” Macromolecules, vol. 35, no. 15, pp. 5937–5942, 2002. View at Publisher · View at Google Scholar · View at Scopus
  23. J.-C. Chiang and A. G. MacDiarmid, “‘Polyaniline’: protonic acid doping of the emeraldine form to the metallic regime,” Synthetic Metals, vol. 13, no. 1–3, pp. 193–205, 1986. View at Google Scholar · View at Scopus
  24. S.-A. Chen and H.-T. Lee, “Structure and properties of poly(acrylic acid)-doped polyaniline,” Macromolecules, vol. 28, no. 8, pp. 2858–2866, 1995. View at Google Scholar · View at Scopus
  25. M. Avram and G. D. Mateescu, Infrared Spectroscopy: Applications in Organic Chemistry, chapter 4, Wiley-Interscience, New York, NY, USA, 1972.
  26. M. Trchova, I. Sedenkova, E. N. Konyushenko, J. Stejskal, P. Holler, and G. C. Marjanovic, “Evolution of polyaniline nanotubes: the oxidation of Aniline in water,” The Journal of Physical Chemistry B, vol. 110, pp. 9461–9468, 2006. View at Publisher · View at Google Scholar
  27. E. C. Venancio, P.-C. Wang, and A. G. MacDiarmid, “The azanes: a class of material incorporating nano/micro self-assembled hollow spheres obtained by aqueous oxidative polymerization of aniline,” Synthetic Metals, vol. 156, no. 5-6, pp. 357–369, 2006. View at Publisher · View at Google Scholar · View at Scopus
  28. A. J. Epstein, J. Joo, R. S. Kohlman et al., “Inhomogeneous disorder and the modified Drude metallic state of conducting polymers,” Synthetic Metals, vol. 65, no. 2-3, pp. 149–157, 1994. View at Google Scholar · View at Scopus
  29. R. S. Kohlman, J. Joo, Y. G. Min, A. G. MacDiarmid, and A. J. Epstein, “Crossover in electrical frequency response through an insulator-metal transition,” Physical Review Letters, vol. 77, no. 13, pp. 2766–2769, 1996. View at Google Scholar · View at Scopus
  30. J. G. Masters, Y. Sun, A. G. MacDiarmid, and A. J. Epstein, “Polyaniline: allowed oxidation states,” Synthetic Metals, vol. 41, no. 1-2, pp. 715–718, 1991. View at Google Scholar · View at Scopus
  31. Y. Xia, J. M. Wiesinger, A. G. MacDiarmid, and A. J. Epstein, “Camphorsulfonic acid fully doped polyaniline emeraldine salt: conformations in different solvents studied by an ultraviolet/visible/ near-infrared spectroscopic method,” Chemistry of Materials, vol. 7, no. 3, pp. 443–445, 1995. View at Google Scholar · View at Scopus
  32. B. J. Kim, S. G. Oh, M. G. Han, and S. S. Im, “Preparation of polyaniline nanoparticles in micellar solutions as polymerization medium,” Langmure, vol. 16, pp. 5841–5845, 2000. View at Publisher · View at Google Scholar
  33. M. Harada and M. Adachi, “Surfactant-mediated fabrication of Silica nanotubes,” Advanced Materials, vol. 12, pp. 839–841, 2000. View at Publisher · View at Google Scholar
  34. R. H. Baughman, J. F. Wolf, H. Echardt, and L. W. Schaklette, “The structure of a novel polymeric metal: acceptor-doped polyaniline,” Synthetic Metals, vol. 25, pp. 121–137, 1998. View at Publisher · View at Google Scholar
  35. J. P. Pouget, M. E. Józefowicz, A. J. Epstein, X. Tang, and A. G. MacDiarmid, “X-ray structure of polyaniline,” Macromolecules, vol. 24, no. 3, pp. 779–789, 1991. View at Google Scholar · View at Scopus
  36. M. Wan and J. Li, “Microtubules of polyaniline doped with HCl and HBF4,” Journal of Polymer Science A, vol. 37, pp. 4605–4609, 1999. View at Google Scholar
  37. V. I. Krinichnyi, S. D. Chemerisov, and Y. S. Lebedev, “EPR and charge-transport studies of polyaniline,” Physical Review B, vol. 55, no. 24, pp. 16233–16244, 1997. View at Google Scholar · View at Scopus
  38. J. Joo, H. G. Song, Y. C. Chung et al., “The effects of Dopant and solvent on charge transport of Doped polyanilines,” Journal of the Korean Physical Society, vol. 30, pp. 230–236, 1997. View at Google Scholar
  39. J. Stejskal, I. Sapurina, M. Trchova, J. Prokes, I. Krivka, and E. Tobolkova, “Solid-state protonation and electrical conductivity of polyaniline,” Macromolecules, vol. 31, no. 7, pp. 2218–2222, 1998. View at Publisher · View at Google Scholar · View at Scopus
  40. W. Lee, G. Du, S. M. Long et al., “Charge transport properties of fully-sulfonated polyaniline,” Synthetic Metals, vol. 84, no. 1–3, pp. 807–808, 1997. View at Google Scholar · View at Scopus
  41. Z. H. Wang, C. Li, E. M. Scherr, A. G. MacDiarmid, and A. J. Epstein, “Three dimensionality of “metallic” states in conducting polymers: polyaniline,” Physical Review Letters, vol. 66, no. 13, pp. 1745–1748, 1991. View at Google Scholar · View at Scopus
  42. K. P. Nazeer, S. A. Jacob, M. Thamilselvan, D. Mangalaraj, S. K. Narayandass, and J. Yi, “Space-charge limited conduction in polyaniline films,” Polymer International, vol. 53, no. 7, pp. 898–902, 2004. View at Publisher · View at Google Scholar · View at Scopus
  43. B. Sanjai, A. Raghunathan, T. S. Natarajan et al., “Charge transport and magnetic properties in polyaniline doped with methane sulphonic acid and polyaniline-polyurethane blend,” Physical Review B, vol. 55, no. 16, pp. 10734–10744, 1997. View at Google Scholar · View at Scopus
  44. S. Kim and I. J. Chung, “Annealing effect on the electrochemical property of polyaniline complexed with various acids,” Synthetic Metals, vol. 97, no. 2, pp. 127–133, 1998. View at Google Scholar