Table of Contents
Indian Journal of Materials Science
Volume 2014 (2014), Article ID 124065, 6 pages
http://dx.doi.org/10.1155/2014/124065
Research Article

Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization Analysis on Anticorrosive Activity of Thiophene-2-Carbaldehyde Derivative in Acid Medium

Research Division, Department of Chemistry, St.Thomas’ College University of Calicut Thrissur, Kerala 680001, India

Received 18 September 2013; Accepted 16 December 2013; Published 2 February 2014

Academic Editors: A. Chatterji and A. M. Stephan

Copyright © 2014 Nimmy Kuriakose et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The corrosion inhibition efficiency of thiophene-2-carbaldehyde tryptophan (T2CTRY) on mild steel (MS) in 1 M HCl solution has been investigated and compared using weight loss measurements, electrochemical impedance spectroscopy, and potentiodynamic polarization analysis. The Schiff base exhibited very good corrosion inhibition on mild steel in HCl medium and the inhibition efficiency increased with the increase in concentration of the inhibitor. The adsorption of the inhibitor on the surface of the corroding metal obeys Freundlich isotherm. Thermodynamic parameters ( , Δ ) were calculated using adsorption isotherm. Polarization studies revealed that T2CTRY acts as a mixed type inhibitor. A maximum of 96.2% inhibition efficiency was achieved by EIS studies at a concentration of 1 mM.