Table of Contents
International Journal of Spectroscopy
Volume 2011, Article ID 568913, 12 pages
http://dx.doi.org/10.1155/2011/568913
Research Article

Molecular Laser Spectroscopy as a Tool for Gas Analysis Applications

1Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116 Braunschweig, Germany
2Floralis, Filiale de l'Université Joseph Fourier, Grenoble, 6 allée de Bethléem, 38610 Gières, France
33LIPhy-Laboratory of Interdisciplinary Physics (formerly LSP), CNRS Unité Mixte de Recherche 5588, 140 rue de la Physique, Batiment E45 Université J. Fourier de Grenoble 38402 St Martin d'Hères, France

Received 25 January 2011; Accepted 28 March 2011

Academic Editor: Veronica Vaida

Copyright © 2011 Javis Anyangwe Nwaboh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. Duxbury, N. Langford, M. T. McCulloch, and S. Wright, “Rapid passage induced population transfer and coherences in the 8 micron spectrum of nitrous oxide,” Molecular Physics, vol. 105, no. 5–7, pp. 741–754, 2007. View at Publisher · View at Google Scholar · View at Scopus
  2. W. Demtröder, Laser Spectroscopy: Basic Principles, vol. 1, Springer, Berlin, Germany, 4th edition, 2008.
  3. K. McCann, M. Wagner, A. Guerra et al., “Spectroscopic investigations and potential energy surfaces of the ground and excited states of 1,3-benzodioxan,” Journal of Chemical Physics, vol. 131, no. 4, Article ID 044302, 2009. View at Google Scholar
  4. V. A. Kapitanov, A. M. Solodov, T. M. Petrova, and Y. N. Ponomarev, “Fourier transform and photoacoustic absorption spectra of ethylene within 6035-6210 cm−1: comparative measurements,” International Journal of Spectroscopy, vol. 2010, Article ID 203672, 6 pages, 2010. View at Publisher · View at Google Scholar
  5. K. L. Plath, K. Takahashi, R. T. Skodje, and V. Vaida, “Fundamental and overtone vibrational spectra of gas-phase pyruvic acid,” Journal of Physical Chemistry A, vol. 113, no. 26, pp. 7294–7303, 2009. View at Publisher · View at Google Scholar · View at Scopus
  6. M. Gharavi and S. G. Buckley, “Diode laser absorption spectroscopy measurement of linestrengths and pressure broadening coefficients of the methane 2ν3 band at elevated temperatures,” Journal of Molecular Spectroscopy, vol. 229, no. 1, pp. 78–88, 2005. View at Publisher · View at Google Scholar · View at Scopus
  7. X. Li, K. L. C. Hunt, F. Wang, M. Abel, and L. Frommhold, “Collision-induced infrared absorption by molecular hydrogen pairs at thousands of kelvin,” International Journal of Spectroscopy, vol. 2010, Article ID 371201, 11 pages, 2010. View at Publisher · View at Google Scholar
  8. F. Huisken, M. Kaloudis, M. Koch, and O. Werhahn, “Experimental study of the O-H ring vibrations of the methanol trimer,” Journal of Chemical Physics, vol. 105, no. 19, pp. 8965–8968, 1996. View at Google Scholar · View at Scopus
  9. F. Huisken, S. A. Krasnokutski, A. Y. Ivanov, and O. Werhahn, “The O-H stretching vibrations of glycine trapped in rare gas matrices and helium clusters,” Journal of Chemical Physics, vol. 111, no. 7, pp. 2978–2984, 1999. View at Google Scholar · View at Scopus
  10. J. Manne, O. Sukhorukov, W. Jäger, and J. Tulip, “Pulsed quantum cascade laser-based cavity ring-down spectroscopy for ammonia detection in breath,” Applied Optics, vol. 45, no. 36, pp. 9230–9237, 2006. View at Publisher · View at Google Scholar · View at Scopus
  11. I. Ventrillard-Courtillot, T. Gonthiez, C. Clerici, and D. Romanini, “Multispecies breath analysis faster than a single respiratory cycle by optical-feedback cavity-enhanced absorption spectroscopy,” Journal of Biomedical Optics, vol. 14, no. 6, Article ID 064026, 2009. View at Google Scholar · View at Scopus
  12. M. L. Silva, D. M. Sonnenfroh, D. I. Rosen, M. G. Allen, and A. O'Keefe, “Integrated cavity output spectroscopy measurements of nitric oxide levels in breath with a pulsed room-temperature quantum cascade laser,” Applied Physics B, vol. 81, no. 5, pp. 705–710, 2005. View at Publisher · View at Google Scholar · View at Scopus
  13. G. Wysocki, A. A. Kosterev, and F. K. Tittel, “Spectroscopic trace-gas sensor with rapidly scanned wavelengths of a pulsed quantum cascade laser for in situ NO monitoring of industrial exhaust systems,” Applied Physics B, vol. 80, no. 4–5, pp. 617–625, 2005. View at Publisher · View at Google Scholar · View at Scopus
  14. G. Maisons, P. Gorrotxategi Carbajo, M. Carras, and D. Romanini, “Optical-feedback cavity-enhanced absorption spectroscopy with a quantum cascade laser,” Optics Letters, vol. 35, no. 21, pp. 3607–3609, 2010. View at Google Scholar
  15. B. W. M. Moeskops, H. Naus, S. M. Cristescu, and F. J. M. Harren, “Quantum cascade laser-based carbon monoxide detection on a second time scale from human breath,” Applied Physics B, vol. 82, pp. 649–654, 2006. View at Google Scholar
  16. G. Wysocki, M. McCurdy, S. So et al., “Pulsed quantum-cascade laser-based sensor for trace-gas detection of carbonyl sulfide,” Applied Optics, vol. 43, no. 32, pp. 6040–6046, 2004. View at Publisher · View at Google Scholar · View at Scopus
  17. S. Kassi, M. Chenevier, L. Gianfrani, A. Salhi et al., “Looking into the volcano with a Mid-IR DFB diode laser and cavity enhanced absorption spectroscopy,” Optics Express, vol. 14, no. 23, pp. 11442–11452, 2006. View at Publisher · View at Google Scholar · View at Scopus
  18. K. Wunderle, S. Wagner, I. Pasti et al., “Distributed feedback diode laser spectrometer at 2.7?µm for sensitive, spatially resolved H2O vapor detection,” Applied Optics, vol. 48, no. 4, pp. B172–B182, 2009. View at Publisher · View at Google Scholar · View at Scopus
  19. M. R. McCurdy, Y. Bakhirkin, G. Wysocki, and F. K. Tittel, “Performance of an exhaled nitric oxide and carbon dioxide sensor using quantum cascade laser-based integrated cavity output spectroscopy,” Journal of Biomedical Optics, vol. 12, no. 3, Article ID 034034, 2007. View at Publisher · View at Google Scholar · View at Scopus
  20. R. Q. Iannone, S. Kassi, H. J. Jost et al., “Development and airborne operation of a compact water isotope ratio infrared spectrometer,” Isotopes in Environmental and Health Studies, vol. 45, no. 4, pp. 303–320, 2009. View at Google Scholar · View at Scopus
  21. V. Weldon, J. O'Gorman, P. Phelan, J. Hegarty, and T. Tanbun-Ek, “H2S and CO2 gas sensing using DFB laser diodes emitting at 1.57 μm,” Sensors and Actuators B, vol. 29, no. 1–3, pp. 101–107, 1995. View at Google Scholar · View at Scopus
  22. M. Sowa, M. Mürtz, and P. Hering, “Mid-infrared laser spectroscopy for online analysis of exhaled CO,” Journal of Breath Research, vol. 4, no. 4, Article ID 047101, 2010. View at Google Scholar
  23. C. E. Miller, L. R. Brown, R. A. Toth, D. C. Benner, and V. M. Devi, “Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the orbiting carbon observatory (OCO) experiment,” Comptes Rendus Physique, vol. 6, no. 8, pp. 876–887, 2005. View at Publisher · View at Google Scholar · View at Scopus
  24. D. Crisp, R. M. Atlas, F. M. Breon et al., “The orbiting carbon observatory (OCO) mission,” Advances in Space Research, vol. 34, no. 4, pp. 700–709, 2004. View at Publisher · View at Google Scholar · View at Scopus
  25. R. A. Toth, C. E. Miller, L. R. Brown, V. M. Devi, and D. C. Benner, “Line strengths of 16O13C16O, 16O13C18O, 16O13C17O and 18O13C18O between 2200 and 6800 cm−1,” Journal of Molecular Spectroscopy, vol. 251, no. 1–2, pp. 64–89, 2008. View at Publisher · View at Google Scholar · View at Scopus
  26. E. R. Crosson, K. N. Ricci, B. A. Richman et al., “Stable isotope ratios using cavity ring-down spectroscopy: determination of 13C/12C for carbon dioxide in human breath,” Analytical Chemistry, vol. 74, no. 9, pp. 2003–2007, 2002. View at Publisher · View at Google Scholar · View at Scopus
  27. K. Heinrich, T. Fritsch, P. Hering, and M. Mürtz, “Infrared laser-spectroscopic analysis of 14NO and 15NO in human breath,” Applied Physics B, vol. 95, no. 2, pp. 281–286, 2009. View at Publisher · View at Google Scholar · View at Scopus
  28. A. Predoi-Cross, C. Hnatovsky, K. Strong, J. R. Drummond, and D. Chris Benner, “Temperature dependence of self- and N2-broadeningand pressure-induced shifts in the 3 0 band of CO,” Journal of Molecular Structure, vol. 695–696, pp. 269–286, 2004. View at Publisher · View at Google Scholar · View at Scopus
  29. O. Werhahn and J. C. Petersen, Eds., TILSAM Technical Protocol, Version 1.0, PTB: Physikalisch-Technische Bundesanstalt, Braunschweig, Germany, 2010, http://www.euramet.org/fileadmin/docs/projects/934_METCHEM_Interim_Report.pdf.
  30. EURAMET-934, TILSAM—Traceable Infrared Laser Spectrometric Amount Fraction Measurement, 2008, http://www.euramet.orgproject no. 934.
  31. J. A. Nwaboh, O. Werhahn, and D. Schiel, “Measurement of CO amount fractions using a pulsed quantum-cascade laser operated in the intrapulse mode,” Applied Physics B, 2010. View at Publisher · View at Google Scholar
  32. P. Ortwein, W. Woiwode, S. Fleck et al., “Absolute diode laser-based in situ detection of HCl in gasification processes,” Experiments on Fluids, vol. 49, no. 4, pp. 961–968. View at Publisher · View at Google Scholar
  33. Joint Committee for Guides in Metrology (JCGM), “Evaluation of measurement data—guide to the expression of uncertainty in measurement, GUM 1995 with minor corrections, ISO IEC Guide 98-3,” JCGM 100:2008, 2008, http://www.bipm.org/en/publications/guides/gum.html.
  34. L. S. Rothman et al., “HITRAN2008,” Journal of Qauntitative Spectroscopy and Radiative Transfer, vol. 110, pp. 533–572, 2009, http://www.cfa.harvard.edu/HITRAN/. View at Google Scholar
  35. N. Jacquinet-Husson, N. A. Scott, A. Chédin et al., “The GEISA spectroscopic database: current and future archive for earth and planetary atmosphere studies,” Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 109, no. 6, pp. 1043–1059, 2008. View at Publisher · View at Google Scholar · View at Scopus
  36. G. J. Padilla-Víquez, J. Koelliker-Delgado, O. Werhahn, K. Jousten, and D. Schiel, “Traceable CO2-R (12) line intensity for laser-spectroscopy-based gas analysis near 2 μm,” IEEE Transactions on Instrumentation and Measurement, vol. 56, no. 2, pp. 529–533, 2007. View at Publisher · View at Google Scholar · View at Scopus
  37. G. Casa, D. A. Parretta, A. Castrillo, R. Wehr, and L. Gianfrani, “Highly accurate determinations of CO2 line strengths using intensity-stabilized diode laser absorption spectrometry,” Journal of Chemical Physics, vol. 127, no. 8, Article ID 084311, 2007. View at Publisher · View at Google Scholar · View at Scopus
  38. “EMRP Call 2010 Industry and Environment,” 2010, http://www.emrponline.eu/call2010/srte.html.
  39. L. S. Rothman, N. Jacquinet-Husson, C. Boulet, and A. M. Perrin, “History and future of the molecular spectroscopic databases,” Comptes Rendus Physique, vol. 6, no. 8, pp. 897–907, 2005. View at Publisher · View at Google Scholar · View at Scopus
  40. C. Wang and P. Sahay, “Breath analysis using laser spectroscopic techniques: breath biomarkers, spectral fingerprints, and detection limits,” Sensors, vol. 9, no. 10, pp. 8230–8262, 2009. View at Publisher · View at Google Scholar · View at Scopus
  41. S. Welzel, G. Lombardi, P. B. Davies, R. Engeln, D. C. Schram, and J. Röpcke, “Trace gas measurements using optically resonant cavities and quantum cascade lasers operating at room temperature,” Journal of Applied Physics, vol. 104, no. 9, Article ID 093115, 2008. View at Publisher · View at Google Scholar · View at Scopus
  42. T. Fritsch, P. Hering, and M. Mürtz, “Infrared laser spectroscopy for online recording of exhaled carbon monoxide: a progress report,” Journal of Breath Research, vol. 1, no. 1, Article ID 014002, 2007. View at Google Scholar
  43. J. Manne, W. Jäger, and J. Tulip, “Sensitive detection of ammonia and ethylene with a pulsed quantum cascade laser using intra and interpulse spectroscopic techniques,” Applied Physics B, vol. 94, no. 2, pp. 337–344, 2009. View at Publisher · View at Google Scholar · View at Scopus
  44. S. Crunaire, J. Tarmoul, C. Fittschen, A. Tomas, B. Lemoine, and P. Coddeville, “Use of cw-CRDS for studying the atmospheric oxidation of acetic acid in a simulation chamber,” Applied Physics B, vol. 85, no. 2–3, pp. 467–476, 2006. View at Publisher · View at Google Scholar · View at Scopus
  45. A. Foltynowicz, W. Ma, and O. Axner, “Characterization of fiber-laser-based sub-doppler NICE-OHMS for quantitative trace gas detection,” Optics Express, vol. 16, no. 19, pp. 14689–14702, 2008. View at Publisher · View at Google Scholar · View at Scopus
  46. V. Rozanov and A. Rozanov, “Differential optical absorption spectroscopy (DOAS) and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration,” Atmospheric Measurement Techniques, vol. 3, pp. 751–780, 2010, http://www.doas-bremen.de/doas_tutorial.htm. View at Google Scholar
  47. M. Berglund and M. E. Wieser, “Isotopic compositions of elements 2009 (IUPAC Technical report),” Pure and Applied Chemistry, vol. 83, no. 2, pp. 397–410, 2011. View at Publisher · View at Google Scholar
  48. ISO 6143: 2001, Gas analysis: comparison methods for determining and checking the composition of calibration gas mixtures, International Organization for Standardization, Geneva, Switzerland, 2001.
  49. Origin 7.5 SR6, OriginLab Cooperation, Northampton, Mass, USA, 2006.
  50. K. Namjou, S. Cai, E. A. Whittaker et al., “Sensitive absorption spectroscopy with a room-temperature distributed-feedback quantum-cascade laser,” Optics Letters, vol. 23, no. 3, pp. 219–223, 1998. View at Google Scholar · View at Scopus
  51. D. D. Nelson, J. H. Shorter, J. B. Mcmanus, and M. S. Zahniser, “Sub-part-per-billion detection of nitric oxide in air using a thermoelectrically cooled mid-infrared quantum cascade laser spectrometer,” Applied Physics B, vol. 75, pp. 343–350, 2002. View at Google Scholar
  52. E. Normand, M. McCulloch, G. Duxbury, and N. Langford, “Fast, real-time spectrometer based on a pulsed quantum-cascade laser,” Optics Letters, vol. 28, no. 1, pp. 16–18, 2003. View at Google Scholar · View at Scopus
  53. M. T. McCulloch, E. L. Normand, N. Langford, G. Duxbury, and D. A. Newnham, “Highly sensitive detection of trace gases using the time-resolved frequency downchirp from pulsed quantum-cascade lasers,” Journal of the Optical Society of America B, vol. 20, no. 8, pp. 1761–1768, 2003. View at Google Scholar · View at Scopus
  54. B. Grouiez, B. Parvitte, L. Joly, D. Courtois, and V. Zeninari, “Comparison of a quantum cascade laser used in both cw and pulsed modes. applications to the study of SO2 lines around 9 μm,” Applied Physics B, vol. 90, pp. 177–186, 2008. View at Google Scholar
  55. J. Wagner, CH. Mann, M. Rattunde, and G. Weimann, “Infrared semiconductor lasers for sensing and diagnostics,” Applied Physics A, vol. 78, no. 4, pp. 505–512, 2004. View at Publisher · View at Google Scholar · View at Scopus
  56. A. Evans, J. S. Yu, S. Slivken, and M. Razeghi, “Continuous-wave operation of λ ~ 4.8 μm quantum-cascade lasers at room temperature,” Applied Physics Letters, vol. 85, no. 12, pp. 2166–2168, 2004. View at Publisher · View at Google Scholar · View at Scopus
  57. T. Aellen, S. Blaser, M. Beck, D. Hofstetter, J. Faist, and E. Gini, “Continuous-wave distributed-feedback quantum-cascade lasers on a Peltier cooler,” Applied Physics Letters, vol. 83, no. 10, pp. 1929–1931, 2003. View at Publisher · View at Google Scholar · View at Scopus
  58. E. Theocharous, J. Ish II, and N. P. Fox, “Absolute linearity measurements on HgCdTe detectors in the infrared region,” Applied Optics, vol. 43, no. 21, pp. 4182–4188, 2004. View at Publisher · View at Google Scholar · View at Scopus
  59. S. Welzel, New Enhanced sensitivity infrared laser spectroscopy techniques applied to reactive plasmas and trace gas detection, Ph.D. thesis, Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany, 2009.
  60. G. Berden and R. Engeln, Eds., Cavity Ring-Down Spectroscopy: Techniques and Applications, John Wiley & Sons, Chichester, UK, 2009.
  61. R. D. van Zee and J. Patrick Looney, “Cavity-enhanced spectroscopies,” in Experimental Methods in the Physical Sciences, vol. 40, Academic Press, Amsterdam, The Netherlands, 2002. View at Google Scholar
  62. J. Morville, S. Kassi, M. Chenevier, and D. Romanini, “Fast, low-noise, mode-by-mode, cavity-enhanced absorption spectroscopy by diode-laser self-locking,” Applied Physics B, vol. 80, no. 8, pp. 1027–1038, 2005. View at Publisher · View at Google Scholar · View at Scopus
  63. Directive 2000/69/EC of the european parliament and of the council of 16 november 2000 relating to limit values for benzene and carbon monoxide in ambient air, Official Journal of the European Communities, 2000, http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2000:313:0012:0021:EN:PDF.
  64. J. Henningsen and H. Simonsen, “The (2201-0000) band of CO2 at 6348 cm−1: Linestrengths, broadening parameters, and pressure shifts,” Journal of Molecular Spectroscopy, vol. 203, no. 1, pp. 16–17, 2000. View at Publisher · View at Google Scholar · View at Scopus
  65. Breath analysis as a diagnostic tool for early disease detection Joint Research Projects funded under iMERA-plus, T2.J02, 2010http://www.euramet.org/index.php?id=1011.
  66. P. Ortwein, W. Woiwode, S. Wagner, M. Gisi, and V. Ebert, “Laser-based measurements of line strength, self and pressure-broadening coefficients of the H35Cl R(3) absorption line in the first overtone region for pressures up to 1 MPa,” Applied Physics B, vol. 100, no. 2, pp. 341–347, 2010. View at Google Scholar
  67. D. Lisak, D. K. Havey, and J. T. Hodges, “Spectroscopic line parameters of water vapor for rotation-vibration transitions near 7180 cm−1,” Physical Review A, vol. 79, no. 5, Article ID 052507, 2009. View at Publisher · View at Google Scholar · View at Scopus
  68. T. Laurila, Ed., “14th WMO/IAEA meeting of experts on carbon dioxide, other greenhouse gases and related tracer measurement techniques,” GAW Report 186, World Meteorological Organization (WMO), Geneva, Switzerland, 2009, http://www.wmo.int/pages/prog/arep/gaw/gaw-reports.html. View at Google Scholar