Research Article
Synthesis, Characterization, and Crystal Structure of a Diorganotin(IV) Complex with 2-Oxo-2-Phenylacetic Acid 4-Hydroxybenzohydrazone
Table 1
Crystal data and structure refinement for complex 1.
| | Complex | 1 |
| | Empirical formula | C27H40N2O6Sn | | Formula weight | 607.30 | | Temperature (K) | 298(2) | | Crystal system | Triclinic | | Space group | P-1 |
| | Unit cell dimensions |
| | (Å) | 9.3220(10) | | (Å) | 9.8779(11) | | (Å) | 15.9401(17) | | (°) | 100.622(2) | | (°) | 97.0930(10) | | (°) | 92.8550(10) | | Volume (Å3) | 1427.6(3) | | Z | 2 | | Calculated d (g/cm3) | 1.413 | | Absorption coefficient (mm−1) | 0.936 | | F (000) | 628 | | Crystal size (mm) | 0.50 × 0.46 × 0.41 | | Theta range for data collection (°) | 2.21–25.02 | | Limiting indices | −11 ≤ h ≤ 11 | | −11 ≤ k ≤ 9 | | −15 ≤ l ≤ 18 | | Reflections collected/unique | 7006/4855 [R(int) = 0.0887] | | Completeness to theta = 25.02° | 96.3% | | Absorption correction | Semi-empirical from equivalents | | Max. and min. transmission | 0.7002 and 0.6519 | | Refinement method | Full-matrix least-squares on F2 | | Data/restraints/parameters | 4855/0/330 | | Goodness-of-fit on F2 | 1.031 | | Final R indices [I > 2σ(I)] | R1 = 0.1158, wR2 = 0.2522 | | R indices (all data) | R1 = 0.2161, wR2 = 0.3313 | Largest diff. peak and hole
(eÅ−3) | 1.446 and −1.923 |
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