Research Article

Secondary Relaxation inside the Glass

Table 2

Activation enthalpy ( Δ 𝐻 𝛽 ) and activation entropy, Δ 𝑆 𝛽 , of the studied secondary processes at the different pressure values.

P ( MPa) Δ 𝐻 𝛽 (KJ/mol) Δ 𝑆 𝛽 (J/mol/K)

PPGE500 6 3 ± 2 2 1 . 6 ± 0 . 5
0.1 5 0 . 8 ± 0 . 6 2 1 . 3 ± 0 . 2
PDE500 5 9 . 0 ± 0 . 9 1 3 . 0 ± 0 . 3
0.1 5 1 ± 1 2 2 ± 0 . 3
BMPC500 4 9 . 4 ± 0 . 4 3 . 0 ± 0 . 2
0.1 4 7 . 0 ± 0 . 5 4 . 4 ± 0 . 1
PVAc400 4 9 ± 1 1 1 . 3 ± 0 . 2
300 4 9 ± 2 1 4 . 6 ± 0 . 4
0.1 3 9 . 1 ± 0 . 1 6 . 2 ± 0 . 1
DGBEA400 5 2 ± 1 1 2 . 0 ± 0 . 2
0.1 4 7 . 1 ± 0 . 5 1 6 . 6 ± 0 . 2
PPG4000.1 2 9 . 5 ± 0 . 5 1 1 . 2 ± 0 . 2