Research Article

Applicability of Scaling Approach for Analysis of Pyrolysis and Gasification of Porous Structures Composed of Solid Fuel Particles

Table 2

Parameters of the pyrolysis approximations obtained with the three kinetic models.

S/F agent 𝑇 (°C)RPMGMVM
𝑅 2 𝜓 𝑘 0 (s−1) 𝐸 𝑎 (J/Mol) 𝑅 2 FF 𝑘 0 (s−1) 𝐸 𝑎 (J/Mol) 𝑅 2 𝑘 0 (s−1) 𝐸 𝑎 (J/Mol)

1.8757670.9960.5684900230.9950.3382900690.9949367130000
8300.9922.3455900240.9910.3363900670.9865381130000
9130.9850.175900200.9670.3358900620.9844508130000

3.27950.9850.1108900210.9690.336861080120.9861485113000
8760.99310.4230900240.9760.333851080370.935790113000
9060.9947.4140900230.9750.334301080320.935868113000

Argon7880.97945.085041140000.9630.335071045280.938950109000
8330.9443.295011140000.9640.854521045320.881451109002
9170.99611.193101144990.9960.844251045320.916418109004