Table of Contents
ISRN Thermodynamics
Volume 2012 (2012), Article ID 323916, 8 pages
http://dx.doi.org/10.5402/2012/323916
Research Article

Thermogravimetric and Spectroscopic Analysis of 8-Hydroxyquinoline 5-Sulphonic Acid-melamine-formaldehyde Polymer Resin-IV

R.D College of Science, Aheri, Gadchiroli, Nagpur, Maharashtra 442705, India

Received 11 December 2011; Accepted 2 January 2012

Academic Editors: Y. Fang, E. Gallicchio, S. Hashimoto, and P. Trens

Copyright © 2012 Rajesh N. Singru. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The title terpolymer (8-HQ5-SAMF-IV) synthesized by the condensation of 8-hydroxyquinoline 5-sulphonic acid (8-HQ5-SA) and melamine (M) with formaldehyde (F) in the presence of acid catalyst and using varied 3 : 1 : 5 molar proportions of the reacting monomers. The synthesized terpolymer was characterized by different physicochemical techniques. The thermogravimetric analysis of terpolymer resin prepared in the present study has been carried out by nonisothermal thermogravimetric analysis technique in which sample is subjected to condition of continuous increase in temperature at linear rate. Thermal study of the resin was carried out to determine the mode of decomposition and thermal stability. Thermal decomposition curve was studied carefully with minute details. The Freeman-Carroll and Sharp-Wentworth methods have been used in the present investigation to calculate thermal activation energy and different kinetic parameter of the terpolymer resin. Thermal activation energy ( ๐ธ a ) calculated by two above mentioned methods, is in close agreement. The advantage of Freeman-Carroll method is to calculate both the order of reaction (n) and energy of activation in one single stage by keeping heating rate constant. By using data of thermogravimetric analysis, various thermogravimetric parameters like frequency factor (Z), entropy change (ΔS), free energy change (ΔF), and apparent entropy ( ๐‘† โˆ— ) have been determined using Freeman-Carroll method.