International Scholarly Research Notices / 2012 / Article / Tab 1 / Research Article
Verification, Validation, and Testing of Kinetic Mechanisms of Hydrogen Combustion in Fluid-Dynamic Computations Table 1 New skeletal mechanism.
No Reference no Reaction
𝐴
𝑛
𝐸
𝑎
Reference 1 R1
H
+
O
2
→
O
H
+
O
1
.
9
1
𝑒
+
1
4
0.0 16.44 [30 ] 2 R2
H
2
+
O
→
H
+
O
H
2
5
.
0
8
𝑒
+
4
2.67 6.292 [30 ] 3 R3
H
2
+
O
H
→
H
+
H
2
O
2
.
1
6
𝑒
+
8
1.51 3.43 [30 ] 4 R5
H
2
+
M
↔
H
+
H
+
M
4
.
5
7
𝑒
+
1
9
−1.4 105.1 [13 ] 5 R6
O
+
O
+
M
↔
O
2
+
M
6
.
1
7
𝑒
+
1
5
−0.5 0.0 [13 ] 6 R7
H
+
O
+
M
→
O
H
+
M
4
.
7
2
𝑒
+
1
8
−1.0 0.0 [13 ] 7 R8
H
+
O
H
+
M
→
H
2
O
+
M
4
.
5
𝑒
+
2
2
−2.0 0.0 [13 ] 8 R9
H
+
O
2
+
M
→
H
O
2
+
M
6
.
1
7
𝑒
+
1
9
−1.42 0.0 [30 ] 9 R10
H
+
H
O
2
→
H
2
+
O
2
1
.
6
6
𝑒
+
1
3
0.0 0.82 [13 ] 10 R-10
H
2
+
O
2
→
H
+
H
O
2
3
.
6
8
𝑒
+
1
3
0.203 54.46 [30 ] 11 R11
H
+
H
O
2
→
O
H
+
O
H
1
.
6
9
𝑒
+
1
4
0.0 0.87 [30 ] 12 R13
O
H
+
H
O
2
→
H
2
O
+
O
2
2
.
8
9
𝑒
+
1
3
0.0 −0.5 [13 ] 13 R15
H
2
O
2
+
M
→
O
H
+
O
H
+
M
1
.
2
𝑒
+
1
7
0.0 45.5 [30 ] 14 R-17
H
2
+
H
O
2
→
H
+
H
2
O
2
3
.
4
2
𝑒
+
1
2
0.202 27.12 [30 ]
𝑘
=
𝐴
⋅
𝑇
𝑛
⋅
e
x
p
(
−
𝐸
𝑎
/
𝑅
𝑇
)
; units: mol,
c
m
3
, K, and kcal; thermodynamic data [5 ]; the reverse rate constants (R5, R6) are calculated from the forward rate constants through the equilibrium constants.
