International Scholarly Research Notices / 2012 / Article / Tab 1

Research Article

Verification, Validation, and Testing of Kinetic Mechanisms of Hydrogen Combustion in Fluid-Dynamic Computations

Table 1

New skeletal mechanism.

No Reference no Reaction 𝐴 𝑛 𝐸 π‘Ž Reference

1R1 H + O 2 β†’ O H + O 1 . 9 1 𝑒 + 1 4 0.016.44[30]
2R2 H 2 + O β†’ H + O H 2 5 . 0 8 𝑒 + 4 2.676.292[30]
3R3 H 2 + O H β†’ H + H 2 O 2 . 1 6 𝑒 + 8 1.513.43[30]
4R5 H 2 + M ↔ H + H + M 4 . 5 7 𝑒 + 1 9 βˆ’1.4105.1[13]
5R6 O + O + M ↔ O 2 + M 6 . 1 7 𝑒 + 1 5 βˆ’0.50.0[13]
6R7 H + O + M β†’ O H + M 4 . 7 2 𝑒 + 1 8 βˆ’1.00.0[13]
7R8 H + O H + M β†’ H 2 O + M 4 . 5 𝑒 + 2 2 βˆ’2.00.0[13]
8R9 H + O 2 + M β†’ H O 2 + M 6 . 1 7 𝑒 + 1 9 βˆ’1.420.0[30]
9R10 H + H O 2 β†’ H 2 + O 2 1 . 6 6 𝑒 + 1 3 0.00.82[13]
10R-10 H 2 + O 2 β†’ H + H O 2 3 . 6 8 𝑒 + 1 3 0.20354.46[30]
11R11 H + H O 2 β†’ O H + O H 1 . 6 9 𝑒 + 1 4 0.00.87[30]
12R13 O H + H O 2 β†’ H 2 O + O 2 2 . 8 9 𝑒 + 1 3 0.0βˆ’0.5[13]
13R15 H 2 O 2 + M β†’ O H + O H + M 1 . 2 𝑒 + 1 7 0.045.5[30]
14R-17 H 2 + H O 2 β†’ H + H 2 O 2 3 . 4 2 𝑒 + 1 2 0.20227.12[30]

π‘˜ = 𝐴 β‹… 𝑇 𝑛 β‹… e x p ( βˆ’ 𝐸 π‘Ž / 𝑅 𝑇 ) ; units: mol, c m 3 , K, and kcal; thermodynamic data [5]; the reverse rate constants (R5, R6) are calculated from the forward rate constants through the equilibrium constants.