Table of Contents
ISRN Analytical Chemistry
Volume 2012, Article ID 514509, 5 pages
http://dx.doi.org/10.5402/2012/514509
Research Article

On the Importance of Purification of Sodium Polystyrene Sulfonate

1Department of Chemical Engineering, Indian Institute of Technology-Bombay, Powai, Mumbai 400076, India
2Department of Chemical and Polymer Engineering, Birla Institute of Technology-Mesra, Ranchi 835215, India

Received 22 November 2011; Accepted 28 December 2011

Academic Editors: P. Kingshott and M. Volny

Copyright © 2012 Akhil K. Sen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. H. Dautzenberg, W. Jaeger, J. Kotz, B. Philipp, C. Seidel, and D. Stscherbina, Polyelectrolytes Formation, Characterization and Applications, Hanser Publishers, Munich, Germany, 1994.
  2. C. P. Walsh, F. R. Gittes, D. A. Perlmutter, and A. T. Stamey, Campbells Urology, vol. 3, W. B. Saunders, Philadelphia, Pa, USA, 5th edition, 1988.
  3. A. Asnacios, R. Klitzing, and D. Langevin, “Mixed monolayers of polyelectrolytes and surfactants at the air-water interface,” Colloids and Surfaces A, vol. 167, no. 1-2, pp. 189–197, 2000. View at Publisher · View at Google Scholar · View at Scopus
  4. J. A. V. Butler, A. B. Robins, and K. V. Shooter, “The viscous behaviour of dilute solutions of a strong polyelectrolyte (Polystyrene Sulphonate),” Proceedings of the Royal Society of London A, vol. 214, no. 1226, pp. 299–310, 1957. View at Google Scholar
  5. M. Sedlák and E. J. Amis, “Dynamics of moderately concentrated salt-free polyelectrolyte solutions: molecular weight dependence,” The Journal of Chemical Physics, vol. 96, no. 1, pp. 817–825, 1992. View at Google Scholar
  6. D. C. Boris and R. H. Colby, “Rheology of sulfonated polystyrene solutions,” Macromolecules, vol. 31, no. 17, pp. 5746–5755, 1998. View at Google Scholar · View at Scopus
  7. J. Cohen, Z. Priel, and Y. Rabin, “Viscosity of dilute polyelectrolyte solutions,” The Journal of Chemical Physics, vol. 88, no. 11, pp. 7111–7116, 1988. View at Google Scholar · View at Scopus
  8. F. R. Prini and E. A. Lagos, “Tracer diffusion, electrical conductivity, and viscosity of aqueous solutions of polystyrenesulfonates,” Journal of Polymer Science A, vol. 2, no. 6, pp. 2917–2928, 1964. View at Google Scholar
  9. M. Rubinstein, R. H. Colby, and A. V. Dobrynin, “Dynamics of semidilute polyelectrolyte solutions,” Physical Review Letters, vol. 73, no. 20, pp. 2776–2779, 1994. View at Publisher · View at Google Scholar · View at Scopus
  10. H. Vink, “Rheology of dilute polyelectrolyte solutions,” Polymer, vol. 33, no. 17, pp. 3711–3716, 1992. View at Google Scholar · View at Scopus
  11. J. L. M. S. Ganter, M. Milas, and M. Rinaudo, “On the viscosity of sodium poly(styrene sulphonate), a flexible polyelectrolyte,” Polymer, vol. 33, no. 1, pp. 113–116, 1992. View at Google Scholar · View at Scopus
  12. N. Ise and T. Okubo, “Mean activity coefficient of polyelectrolytes. V. Measurements of polyvinyl sulfates of various gegenions,” The Journal of Physical Chemistry, vol. 71, no. 6, pp. 1886–1890, 1967. View at Google Scholar · View at Scopus
  13. N. Ise and T. Okubo, “Mean activity coefficient of polyelectrolytes. VIII. Osmotic and activity coefficients of polystyrenesulfonates of various gegenions,” Journal of Physical Chemistry, vol. 72, no. 4, pp. 1361–1366, 1968. View at Google Scholar · View at Scopus
  14. M. Reddy and J. A. Marinsky, “A further investigation of the osmotic properties of hydrogen and sodium polystyrenesulfonates,” The Journal of Physical Chemistry, vol. 74, no. 22, pp. 3884–3891, 1970. View at Google Scholar · View at Scopus
  15. P. Chu and J. A. Marinsky, “The osmotic properties of polystyrenesulfonates. I. The osmotic coefficients,” Journal of Physical Chemistry, vol. 71, no. 13, pp. 4352–4359, 1967. View at Google Scholar · View at Scopus
  16. T. Okubo, “Surface tension of synthetic polyelectrolyte solutions at the air-water interface,” Journal of Colloid And Interface Science, vol. 125, no. 2, pp. 386–398, 1988. View at Google Scholar · View at Scopus
  17. O. Théodoly, R. Ober, and C. E. Williams, “Adsorption of hydrophobic polyelectrolytes at the air/water interface: conformational effect and history dependence,” European Physical Journal E, vol. 5, no. 1, pp. 51–58, 2001. View at Publisher · View at Google Scholar
  18. H. Yim, M. Kent, A. Matheson et al., “Adsorption of poly(styrenesulfonate) to the air surface of water by neutron reflectivity,” Macromolecules, vol. 33, no. 16, pp. 6126–6133, 2000. View at Publisher · View at Google Scholar · View at Scopus
  19. H. Yim, M. S. Kent, A. Matheson et al., “Adsorption of sodium poly(styrenesulfonate) to the air surface of water by neutron and x-ray reflectivity and surface tension measurements: polymer concentration dependence,” Macromolecules, vol. 35, no. 26, pp. 9737–9747, 2002. View at Publisher · View at Google Scholar · View at Scopus
  20. C. Tondre and R. Zana, “Apparent molal volumes of polyelectrolytes in aqueous solutions,” Journal of Physical Chemistry, vol. 76, no. 23, pp. 3451–3459, 1972. View at Google Scholar · View at Scopus
  21. E. Hirose, Y. Iwamoto, and T. Norisuye, “Chain stiffness and excluded-volume effects in sodium poly(styrenesulfonate) solutions at high ionic strength,” Macromolecules, vol. 32, no. 25, pp. 8629–8634, 1999. View at Google Scholar · View at Scopus
  22. V. M. Prabhu, M. Muthukumar, G. D. Wignall, and Y. B. Melnichenko, “Polyelectrolyte chain dimensions and concentration fluctuations near phase boundaries,” Journal of Chemical Physics, vol. 119, no. 7, pp. 4085–4098, 2003. View at Publisher · View at Google Scholar · View at Scopus
  23. A. K. Sen, Behavior of sodium polystyrene sulfonate in solution and at interfaces, Ph.D. thesis, Indian Institute of Technology, Bombay, India, 2005.
  24. B. A. Noskov, S. N. Nuzhnov, G. Loglio, and R. Miller, “Dynamic surface properties of sodium poly(styrenesulfonate) solutions,” Macromolecules, vol. 37, no. 7, pp. 2519–2526, 2004. View at Publisher · View at Google Scholar · View at Scopus
  25. G. S. Manning, “Limiting laws and counterion condensation in polyelectrolyte solutions I. Colligative properties,” The Journal of Chemical Physics, vol. 51, no. 3, pp. 924–933, 1969. View at Google Scholar · View at Scopus
  26. A. K. Sen, S. Roy, and V. A. Juvekar, “Effect of structure on solution and interfacial properties of sodium polystyrene sulfonate (NaPSS),” Polymer International, vol. 56, no. 2, pp. 167–174, 2007. View at Publisher · View at Google Scholar · View at Scopus