Table of Contents
ISRN Analytical Chemistry
Volume 2012, Article ID 594598, 8 pages
http://dx.doi.org/10.5402/2012/594598
Research Article

Elemental Studies of Soil and Food Flour for Risk Assessment of Highway Pollution Using Particle-Induced X-Ray Emission (PIXE) Spectrometry

1Department of Chemistry, Obafemi Awolowo University, Ile-Ife 220005, Nigeria
2Centre for Energy Research and Development, Obafemi Awolowo University, Ile-Ife 220005, Nigeria

Received 29 December 2011; Accepted 18 January 2012

Academic Editors: A. G. Asuero and R. K. Jyothi

Copyright © 2012 O. I. Asubiojo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. W. H. Rulkens, J. T. C Grotenhuis, and R. Tichy, “Methods for cleaning contaminated soils and sediments,” in Heavy Metals: Problems and Solutions, W. Salomons, U. Forstner, and P. Mader, Eds., pp. 165–191, Springer, Berlin, Germany, 1995. View at Google Scholar
  2. M. Imperato, P. Adamo, D. Naimo, M. Arienzo, D. Stanzione, and P. Violante, “Spatial distribution of heavy metals in urban soils of Naples city (Italy),” Environmental Pollution, vol. 124, no. 2, pp. 247–256, 2003. View at Publisher · View at Google Scholar · View at Scopus
  3. D. S. Manta, M. Angelone, A. Bellanca, R. Neri, and M. Sprovieri, “Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy,” Science of the Total Environment, vol. 300, no. 1–3, pp. 229–243, 2002. View at Publisher · View at Google Scholar · View at Scopus
  4. T. B. Chen, Y. M. Zheng, M. Lei et al., “Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China,” Chemosphere, vol. 60, no. 4, pp. 542–551, 2005. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  5. A. Möller, H. W. Müller, A. Abdullah, G. Abdelgawad, and J. Utermann, “Urban soil pollution in Damascus, Syria: concentrations and patterns of heavy metals in the soils of the Damascus Ghouta,” Geoderma, vol. 124, no. 1-2, pp. 63–71, 2005. View at Publisher · View at Google Scholar
  6. N. Sezgin, H. K. Ozcan, G. Demir, S. Nemlioglu, and C. Bayat, “Determination of heavy metal concentrations in street dusts in Istanbul E-5 highway,” Environment International, vol. 29, no. 7, pp. 979–985, 2004. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  7. L. Borůvka, O. Vacek, and J. Jehlička, “Principal component analysis as a tool to indicate the origin of potentially toxic elements in soils,” Geoderma, vol. 128, no. 3-4, pp. 289–300, 2005. View at Publisher · View at Google Scholar · View at Scopus
  8. J. B. Diatta, E. Chudzinska, and S. Wirth, “Assessment of heavy metal contamination of soils impacted by a zinc smelter activity,” Journal of Elementology, vol. 13, no. 1, pp. 5–17, 2008. View at Google Scholar · View at Scopus
  9. A. A. Olajire, E. T. Ayodele, G. O. Oyedirdan, and A. Oluyemi, “Levels and speciation of heavy metals in soils of industrial Southern Nigeria,” Environmental Monitoring and Assessment, vol. 85, no. 2, pp. 135–155, 2003. View at Publisher · View at Google Scholar
  10. A. A. Olajire and E. T. Ayodele, “Contamination of roadside soil and grass with heavy metals,” Environment International, vol. 23, no. 1, pp. 91–101, 1997. View at Publisher · View at Google Scholar · View at Scopus
  11. A. A. Olajire, “A survey of heavy metal deposition in Nigeria using the moss monitoring method,” Environment International, vol. 24, no. 8, pp. 951–958, 1998. View at Publisher · View at Google Scholar · View at Scopus
  12. A. A. Adeniyi and J. A. Afolabi, “Determination of total petroleum hydrocarbons and heavy metals in soils within the vicinity of facilities handling refined petroleum products in Lagos metropolis,” Environment International, vol. 28, no. 1-2, pp. 79–82, 2002. View at Publisher · View at Google Scholar · View at Scopus
  13. M. D. Dupuis and H. H. Hill, “Analysis of gasoline for antiknock agents with hydrogen atmosphere flame ionization detector,” Analytical Chemistry, vol. 51, no. 2, pp. 292–295, 1979. View at Publisher · View at Google Scholar · View at Scopus
  14. L. M. Shuman, “Organic waste amendments effect on zinc fractions of two soils,” Journal of Environmental Quality, vol. 28, no. 5, pp. 1442–1447, 1999. View at Publisher · View at Google Scholar
  15. H. Howard, “Human health and heavy metals exposure,” in Life support: The Environment and Human Health, Michael McCally, Ed., p. 33, The MIT Press, Cambridge, Mass, USA, 2002. View at Google Scholar
  16. S. Bailey, “The Analysis of agricultural materials,” in A Manual of the Analytical Methods Used by Agricultural and Advisory Services, London, UK, 3rd edition, 1986. View at Google Scholar
  17. QXAS (Quantitative X-ray Analysis System), User Manual, International Atomic Energy Agency (IAEA), Vienna, Austria, 1996.
  18. M. A. Chaudnuri and A. Crawford, Nuclear Instrumental Methods, 1981.
  19. N. C. Brady, The Nature and Properties of Soils, Macmillan Publishing Company, New York, NY, USA, 1984.
  20. F. Adebiyi, O. Asubiojo, T. Ajayi, and E. Obiajunwa, “Trace element and physico-chemical characteristics of the sand and water fractions of Nigerian bituminous sands,” Chemistry and Ecology, vol. 21, no. 5, pp. 369–380, 2005. View at Publisher · View at Google Scholar · View at Scopus
  21. M. K. Fasasi and E. I. Obiajunwa, “Determination of soil to plant transfer rations of major, minor and trace elements in some vegetables grown around Ile-Ife,” Nigerian Journal of Pure and Applied Sciences, vol. 15, pp. 1019–1023, 2000. View at Google Scholar
  22. P. C. Onianwa and J. O. Adoghe, “Heavy-metal content of roadside gutter sediments in Ibadan, Nigeria,” Environment International, vol. 23, no. 6, pp. 873–877, 1997. View at Publisher · View at Google Scholar · View at Scopus
  23. IUGS/IAGC, Annual report for the International Union of Geological Sciences (IUGS)/International Association of Geochemistry (IAGC) Task Group on Global Geochemical Baselines, 2007, http://www.iugc.org/PDF/AR07_IG_GGB.pdf.
  24. Federal Ministry of Agriculture and National Resources, Soil Fertility Investigations in Nigeria (in Five volumes), FMANR, Lagos, Nigeria, 1990.
  25. E. I. Obiajunwa, A. C. Adebajo, and O. R. Omobuwajo, “Essential and trace element contents of some Nigerian medicinal plants,” Journal of Radioanalytical and Nuclear Chemistry, vol. 252, no. 3, pp. 473–476, 2002. View at Publisher · View at Google Scholar · View at Scopus
  26. F. M. Adebiyi, O. I. Asubiojo, and T. R. Ajayi, “Characterization of Nigerian oil sands by TXRF spectrometry,” Petroleum Science and Technology, vol. 26, no. 1, pp. 29–39, 2008. View at Publisher · View at Google Scholar · View at Scopus
  27. N. I. Ward, “Lead contamination of the london orbital (M25) motorway (since its opening in 1986),” Science of the Total Environment, vol. 93, pp. 277–283, 1990. View at Publisher · View at Google Scholar · View at Scopus
  28. O. I. Asubiojo, P. O. Aina, A. F. Oluwole, W. Arshed, O. A. Akanle, and N. M. Spyrou, “Effects of cement production on the elemental composition of soils in the neighborhood of two cement factories,” Water, Air, and Soil Pollution, vol. 57-58, pp. 819–828, 1991. View at Google Scholar · View at Scopus
  29. C. A. Domy, Biogeochemistry of Trace Metals, Lewis, Chelsea, Mich, USA, 1992.
  30. L. S. Sonon and J. Gaskin, “Metal concentration standards for land application of biosolids and other by-products in Georgia,” 2009, http://pubs.caes.uga.edu/caespubs/pdf/B1353.pdf.