Table of Contents
ISRN Polymer Science
Volume 2012 (2012), Article ID 630478, 6 pages
Research Article

Aqueous Photo-Living Radical Polymerization of Sodium Methacrylate Using a Water-Soluble Nitroxide Mediator

Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan

Received 2 March 2012; Accepted 22 March 2012

Academic Editors: B. Hazer, A. V. Popov, D. Radic, and C. T. Ratnam

Copyright © 2012 Eri Yoshida. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The aqueous photo-living radical polymerization of sodium methacrylate (NaMA) was attained using 2,2′-azobis { 2-methyl-N-[1,1-bis(hydroxymethyl)-2-hydroxyethyl]-propionamide } (V-80) as the initiator and 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (HTEMPO) as the mediator in the presence of (4-fluorophenyl)diphenylsulfonium triflate (FS). The polymerization was carried out in water at room temperature by irradiation using a high-pressure mercury lamp. Whereas the polymerization by V-80 and/or FS in the absence of HTEMPO produced polymers with very high molecular weights and broad molecular weight distributions, the HTEMPO-mediated polymerization provided still lower-molecular-weight distributions using both V-80 and FS. The first-order time-conversion plots had an induction period up to 2.5 h; however, they thereafter showed a linear increase. The conversion-molecular weight plots also exhibited a linear correlation. A linear correlation was also obtained for the plots of the molecular weights versus the reciprocal of the initiator concentration. Based on these three correlations, it was found that the HTEMPO-mediated photopolymerization proceeded by a living mechanism.