Table of Contents
ISRN Nanomaterials
Volume 2012, Article ID 769528, 7 pages
http://dx.doi.org/10.5402/2012/769528
Research Article

Synthesis and Characterization of Nanometric Pure Phase SnO2 Obtained from Pyrolysis of Diorganotin(IV) Derivatives of Macrocycles

Department of Chemistry, Indian Institute of Technology, Roorkee 247667, India

Received 11 July 2012; Accepted 27 July 2012

Academic Editors: W. Bao and A. Fidalgo

Copyright © 2012 Mala Nath and P. K. Saini. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. W. Dazhi, W. Shulin, C. Jun, Z. Suyuan, and L. Fangqing, “Microstructure of SnO2,” Physical Review B, vol. 49, no. 20, pp. 14282–14285, 1994. View at Publisher · View at Google Scholar · View at Scopus
  2. D. E. Williams and K. F. E. Pratt, “Classification of reactive sites on the surface of polycrystalline tin dioxide,” Journal of the Chemical Society, Faraday Transactions, vol. 94, pp. 3493–3500, 1998. View at Publisher · View at Google Scholar
  3. T. El Moustafid, H. Cachet, B. Tribollet, and D. Festy, “Modified transparent SnO2 electrodes as efficient and stable cathodes for oxygen reduction,” Electrochimica Acta, vol. 47, no. 8, pp. 1209–1215, 2002. View at Publisher · View at Google Scholar · View at Scopus
  4. A. R. Phani, S. Manorama, and V. J. Rao, “Preparation, characterization and electrical properties of SnO2 based liquid petroleum gas sensor,” Materials Chemistry and Physics, vol. 58, no. 2, pp. 101–108, 1999. View at Publisher · View at Google Scholar
  5. G. J. Li, X. H. Zhang, and S. Kawi, “Relationships between sensitivity, catalytic activity, and surface areas of SnO2 gas sensors,” Sensors and Actuators B, vol. 60, no. 1, pp. 64–70, 1999. View at Publisher · View at Google Scholar · View at Scopus
  6. M. Batzill and U. Diebold, “The surface and materials science of tin oxide,” Progress in Surface Science, vol. 79, no. 2–4, pp. 47–154, 2005. View at Publisher · View at Google Scholar
  7. C. H. Shek, J. K. C. Lai, and G. M. Lin, “Grain growth in nanocrystalline SnO2 prepared by sol-gel route,” Nanostructured Materials, vol. 11, no. 7, pp. 887–893, 1999. View at Publisher · View at Google Scholar
  8. T. Wang, Z. N. X. F. Ma, and Z. Y. Jiang, “The one-step preparation and electrochemical characteristics of tin dioxide nanocrystalline materials,” Electrochemistry Communications, vol. 5, no. 7, pp. 599–602, 2003. View at Publisher · View at Google Scholar
  9. Y. D. Wang, C. L. Ma, X. D. Sun, and H. D. Li, “Preparation and characterization of SnO2 nanoparticles with a surfactant-mediated method,” Nanotechnology, vol. 13, no. 5, article 565, 2002. View at Publisher · View at Google Scholar
  10. U. Kersen, “The gas-sensing potential of nanocrystalline SnO2 produced by a mechanochemical milling via centrifugal action,” Physics and Astronomy, vol. 75, no. 5, pp. 559–563, 2002. View at Publisher · View at Google Scholar
  11. R. D. Tarey and T. A. Raju, “A method for the deposition of transparent conducting thin films of tin oxide,” Thin Solid Films, vol. 128, no. 3-4, pp. 181–189, 1985. View at Google Scholar · View at Scopus
  12. K. Y. Choi, M. J. Kim, D. S. Kim et al., “Preparation and characterization of Nickel(II) and Copper(II) tetaaza macrocyclic complexes with isonicotinate ligands,” Bulletin of the Korean Chemical Society, vol. 23, no. 8, pp. 1062–1066, 2002. View at Publisher · View at Google Scholar
  13. P. V. Bernhardt, J. C. Hetherington, and L. A. Jones, “N-Methylation of diamino-substituted macrocyclic complexes: intramolecular cyclisation,” Journal of the Chemical Society—Dalton Transactions, no. 23, pp. 4325–4330, 1996. View at Google Scholar · View at Scopus
  14. E. Kimura, “Macrocyclic polyamine Zinc(II) complexes as advanced models for Zinc(II) enzymes,” Progress in Inorganic Chemistry, vol. 41, p. 443, 1994. View at Publisher · View at Google Scholar
  15. K. Kumar and M. F. Tweedle, “Ligand basicity and rigidity control formation of macrocyclic polyamino carboxylate complexes of gadolinium(III),” Inorganic Chemistry, vol. 32, pp. 4193–4199, 1993. View at Publisher · View at Google Scholar
  16. A. Bansal and R. V. Singh, “Template synthesis, structural and biological studies of new tetraazamacrocyclic complexes of lead(II),” Boletín de la Sociedad Chilena de Química, vol. 45, no. 3, p. 479, 2000. View at Publisher · View at Google Scholar
  17. M. Shakir, H. T. N. Chishti, and P. Chingsubam, “Metal ion-directed synthesis of 16-membered tetraazamacrocyclic complexes and their physico-chemical studies,” Spectrochimica Acta A, vol. 64, no. 2, pp. 512–517, 2006. View at Publisher · View at Google Scholar · View at Scopus
  18. M. Nath, S. Goyal, G. Eng, and D. Whalen, “Synthesis, spectral, thermal, and biological studies of adducts of organotin(IV) halides with Schiff bases derived from 2-amino-5-(o-methoxyphenyl)-1,3,4-thiadiazole,” Bulletin of the Chemical Society of Japan, vol. 69, no. 3, pp. 605–612, 1996. View at Publisher · View at Google Scholar
  19. A. G. Pereira, L. A. R. Batalha, A. O. Porto et al., “The influence of the R group in the thermal stability of Sn4R4O6 (R = methyl, n-butyl or phenyl),” Materials Research Bulletin, vol. 38, no. 14, pp. 1805–1817, 2003. View at Publisher · View at Google Scholar · View at Scopus
  20. M. Nath and Sulaxna, “Di- and triorganotin(IV) derivatives of 5-amino-3H-1,3,4-thiadiazole-2-thione as precursors for SnS/SnO2: thermal studies and related kinetic parameters,” Materials Research Bulletin, vol. 41, no. 1, pp. 78–91, 2006. View at Publisher · View at Google Scholar
  21. M. Nath, P. K. Saini, G. Eng, and X. Song, “Template synthesis and structural characterization of new diorganotin(IV) tetraazamacrocyclic complexes: precursors to produce pure phase nanosized SnO2,” Journal of Coordination Chemistry, vol. 62, supplement 22, p. 3629, 2009. View at Publisher · View at Google Scholar
  22. M. Nath, P. K. Saini, G. Eng, and X. Song, “Synthesis and solid-state spectroscopic investigation of some novel diorganotin(IV) complexes of tetraazamacrocyclic ligands,” Journal of Organometallic Chemistry, vol. 693, no. 13, pp. 2271–2278, 2008. View at Publisher · View at Google Scholar
  23. H. P. Klug and L. E. Alexander, X-Ray Diffraction Procedures for Polycrystalline and Amorphous Mater, chapter 9, Wiley, New York, NY, USA, 2nd edition, 1974.
  24. H. H. Horowitz and G. Metzger, “A new analysis of thermogravimetric traces,” Analytical Chemistry, vol. 35, no. 10, pp. 1464–1468, 1963. View at Publisher · View at Google Scholar
  25. A. W. Coats and J. P. Redfern, “Kinetic parameters from thermogravimetric data,” Nature, vol. 201, pp. 68–69, 1964. View at Publisher · View at Google Scholar