Effect of Structure of Monocyclic Aromatic Solvents on the Packing Density of Fullerene Solvation Shell
Figure 5
The UV spectra of (1) (C60+o-dichlorobenzene) solution in THF ( and ), (2) the transformed standard spectrum of C60, (3) o-dichlorobenzene corresponding to ( in the λ range from 245 to 285 nm), and (4) o-dichlorobenzene obtained as a difference of (1) and (2) spectra (the calculated value for the spectrum (4) is 1.851 mg/mL). The insert shows the normalized spectrum of o-dichlorobenzene in THF (solid line) and the normalized spectra of o-dichlorobenzene obtained by subtraction of the C60 spectrum from the spectra of (C60+o-dichlorobenzene) solutions in THF with various concentrations of o-dichlorobenzene and C60: , (dash line); , (short dash line); , (dot line).
