Table of Contents
ISRN Inorganic Chemistry
Volume 2013, Article ID 356802, 8 pages
http://dx.doi.org/10.1155/2013/356802
Research Article

Hypercoordinated Organosilicon(IV) and Organotin(IV) Complexes: Syntheses, Spectral Studies, and Antimicrobial Activity In Vitro

1Department of Chemistry, Kurukshetra University, Kurukshetra 136 119, India
2Department of Microbiology, Kurukshetra University, Kurukshetra 136 119, India

Received 27 December 2012; Accepted 14 January 2013

Academic Editors: A. Abu-Surrah, A. Barbieri, A. M. Fonseca, A. Karadag, and S. Turmanova

Copyright © 2013 Kiran Singh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. N. Tandura, M. G. Voronkov, and N. V. Alekseev, “Molecular and electronic structure of penta- and hexacoordinate silicon compounds,” Topics in Current Chemistry, vol. 131, pp. 99–189, 1986. View at Google Scholar
  2. C. Chuit, R. J. P. Corriu, C. Reye, and J. C. Young, “Reactivity of penta- and hexacoordinate silicon compounds and their role as reaction intermediates,” Chemical Reviews, vol. 93, no. 4, pp. 1371–1448, 1993. View at Google Scholar · View at Scopus
  3. W. J. Geary, “The use of conductivity measurements in organic solvents for the characterisation of coordination compounds,” Coordination Chemistry Reviews, vol. 7, no. 1, pp. 81–122, 1971. View at Google Scholar · View at Scopus
  4. J. Wagler, U. Böhme, and G. Roewer, “Activation of a Si-Si bond by hypercoordination: cleavage of a disilane and formation of a Si-C bond,” Organometallics, vol. 23, no. 25, pp. 6066–6069, 2004. View at Publisher · View at Google Scholar · View at Scopus
  5. J. Wagler, D. Gerlach, U. Böhme, and G. Roewer, “Intramolecular interligand charge transfer in hexacoordinate silicon complexes,” Organometallics, vol. 25, no. 12, pp. 2929–2933, 2006. View at Publisher · View at Google Scholar · View at Scopus
  6. M. Jain and R. V. Singh, “Synthesis, characterization, and biotoxicity of NN donor sulphonamide imine, silicon(IV) complexes,” Bioinorganic Chemistry and Applications, vol. 2006, Article ID 13743, 10 pages, 2006. View at Publisher · View at Google Scholar
  7. S. Belwal, N. Fahmi, and R. V. Singh, “Behavioural dynamics in the biological control of pests: role of silicon complexes,” Applied Organometallic Chemistry, vol. 22, no. 11, pp. 615–619, 2008. View at Publisher · View at Google Scholar · View at Scopus
  8. R. V. Singh, M. Jain, and C. N. Deshmukh, “Microwave-assisted synthesis and insecticidal properties of biologically potent organosilicon (IV) compounds of a sulfonamide imine,” Applied Organometallic Chemistry, vol. 19, no. 7, pp. 879–886, 2005. View at Publisher · View at Google Scholar · View at Scopus
  9. A. Chaudhary, A. Phor, S. Gaur, and R. V. Singh, “Isolation, characterization and anti-tumour properties of novel chiral organotin(IV) complexes of phenanthrolines,” Heterocyclic Communications, vol. 10, no. 2-3, pp. 181–186, 2004. View at Google Scholar · View at Scopus
  10. M. Jain, S. Gaur, S. C. Diwedi, S. C. Joshi, R. V. Singh, and A. Bansal, “Nematicidal, insecticidal, antifertility, antifungal and antibacterial activities of salicylanilide sulphathiazole and its manganese, silicon and tin complexes,” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 179, no. 8, pp. 1517–1537, 2004. View at Publisher · View at Google Scholar · View at Scopus
  11. S. T. Blundm, P. A. Cusack, and R. Hill, The Industrial Uses of Tin Chemicals, Royal Society of Chemistry, London, UK, 1985.
  12. R. Joshi, P. Kumar, V. Kumar, and A. A. Hashmi, “Organotin(IV) oxo-homoscorpionate: preparation, spectroscopic characterization and antimicrobial properties,” Journal of Coordination Chemistry, vol. 61, no. 8, pp. 1283–1293, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. T. S. Basu Baul, A. Paul, L. Pellerito et al., “An in vitro comparative assessment with a series of new triphenyltin(IV) 2-/4-[(E)-2-(aryl)-1-diazenyl]benzoates endowed with anticancer activities: structural modifications, analysis of efficacy and cytotoxicity involving human tumor cell lines,” Journal of Inorganic Biochemistry, vol. 107, no. 1, pp. 119–128, 2012. View at Google Scholar
  14. Y. F. Win, S. G. Teoh, E. K. Lim, S. L. Ng, and H. K. Fun, “Synthesis, characterization and crystal structure of the bis(2,4-dinitrobenzoato)tetrabutyldistannoxane(IV) dimer,” Journal of Chemical Crystallography, vol. 38, no. 5, pp. 345–350, 2008. View at Publisher · View at Google Scholar · View at Scopus
  15. K. Singh, Dharampla, and S. S. Dhiman, “Spectral studies and antimicrobial activities of organosilicon(IV) and organotin(IV) complexes of nitrogen and sulfur donor Schiff bases derived from 4-amino-5-mercapto-3-methyl-s-triazole,” Main Group Chemistry, vol. 8, no. 1, pp. 47–59, 2009. View at Publisher · View at Google Scholar · View at Scopus
  16. K. Singh, P. Puri, Y. Kumar, C. Sharma, and K. R. Aneja, “Biological and spectral studies of newly synthesized triazole schiff bases and their Si(IV), Sn(IV) complexes,” Bioinorganic Chemistry and Applications, vol. 2011, Article ID 654250, 10 pages, 2011. View at Publisher · View at Google Scholar
  17. S. Bala, R. P. Gupta, M. L. Sachdeva, A. Singh, and H. K. Pujari, “Heterocyclic systems containing bridgehead nitrogen atom: part 33—syntheses of s-Triazolo[I,3,4]thiadiazine, s-Triazolo[3,4,b][I,3,4]thiadiazino[6,7-b]quinoxaline & as-Triazino [I,3,4]-thiadiazines,” Indian Journal of Heterocyclic Chemistry, vol. 17, no. 1, pp. 79–82, 2007. View at Google Scholar · View at Scopus
  18. M. S. Ahmad, M. Hussain, M. Hanif, S. Ali, and B. Mirza, “Synthesis, chemical characterization and biological screening for cytotoxicity and antitumor activity of organotin (IV) derivatives of 3,4-methylenedioxy 6-nitrophenylpropenoic acid,” Molecules, vol. 12, no. 10, pp. 2348–2363, 2007. View at Publisher · View at Google Scholar · View at Scopus
  19. G. Singh, P. A. Singh, K. Singh, D. P. Singh, R. N. Handa, and S. N. Dubey, “Synthesis and structural studies of some bivalent metal complexes with bidentate Schiff base ligands,” Proceedings of National Academy of Sciences India, vol. 72, no. 2, pp. 87–95, 2002. View at Google Scholar
  20. S. Belwal and R. V. Singh, “Bioactive versatile azomethine complexes of organotin(IV) and organosilicon(IV),” Applied Organometallic Chemistry, vol. 12, no. 1, pp. 39–46, 1998. View at Google Scholar · View at Scopus
  21. M. Jain and R. V. Singh, “Spectral and antimicrobial studies of organosilicon(IV) complexes of a bidentate schiff base having nitrogen-nitrogen donor system,” Main Group Metal Chemistry, vol. 26, no. 4, pp. 237–246, 2003. View at Google Scholar · View at Scopus
  22. A. Chaudhary and R. V. Singh, “Studies on biologically potent tetraazamacrocyclic complexes of bivalent tin,” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 178, no. 3, pp. 615–626, 2003. View at Publisher · View at Google Scholar · View at Scopus
  23. M. Pellei, G. G. Lobbia, M. Ricciutelli, and C. Santini, “Synthesis and spectroscopic characterization of new organotin(IV) complexes with bis(3,5-dimethylpyrazol-1-yl)dithioacetate,” Journal of Coordination Chemistry, vol. 58, no. 5, pp. 409–420, 2005. View at Publisher · View at Google Scholar · View at Scopus
  24. I. Ahmad and A. Z. Beg, “Antimicrobial and phytochemical studies on 45 Indian medicinal plants against multi-drug resistant human pathogens,” Journal of Ethnopharmacology, vol. 74, no. 2, pp. 113–123, 2001. View at Publisher · View at Google Scholar · View at Scopus
  25. M. I. Okeke, C. U. Iroegbu, E. N. Eze, A. S. Okoli, and C. O. Esimone, “Evaluation of extracts of the root of Landolphia owerrience for antibacterial activity,” Journal of Ethnopharmacology, vol. 78, no. 2-3, pp. 119–127, 2001. View at Publisher · View at Google Scholar · View at Scopus
  26. K. R. Aneja, C. Sharma, and R. Joshi, “Fungal infection of the ear: a common problem in the north eastern part of Haryana,” International Journal of Pediatric Otorhinolaryngology, vol. 74, no. 6, pp. 604–607, 2010. View at Publisher · View at Google Scholar · View at Scopus
  27. S. K. S. Al-Burtamani, M. O. Fatope, R. G. Marwah, A. K. Onifade, and S. H. Al-Saidi, “Chemical composition, antibacterial and antifungal activities of the essential oil of Haplophyllum tuberculatum from Oman,” Journal of Ethnopharmacology, vol. 96, no. 1-2, pp. 107–112, 2005. View at Publisher · View at Google Scholar · View at Scopus