Research Article

Hypercoordinated Organosilicon(IV) and Organotin(IV) Complexes: Syntheses, Spectral Studies, and Antimicrobial Activity In Vitro

Table 2

1HNMR chemical shifts of the ligands and their metal complexes.

Compound–CH=N–SHAromatic–HTriazole–CH 2–CH 3, CH 2–CH 2–CH 3

HL110.5611.667.35–8.15(s, d, t)2.85–2.92(q), 1.35–1.40(t)
Me2SiCl(L1)10.897.20–8.04(s, d, t)2.27–2.38(q), 1.12–1.17(t)
Me2Si(L1)211.227.34–8.05(s, d, t)2.29–2.37(q), 1.15–1.20(t)
Me2SnCl(L1)11.047.31–8.05(s, d, t)2.28–2.39(q), 1.12–1.20(t)
Me2Sn(L1)210.877.16–8.05(s, d, t)2.27–2.35(q), 1.13–1.22(t)
HL210.5411.577.35–8.04(s, d, t)2.81–2.85(t), 1.79–1.86(m), 1.03–1.08(t)
Me2SiCl(L2)10.987.34–8.13(s, d, t)2.63–2.68(t), 1.37–1.66(m), 0.90–0.92(t)
Me2Si(L2)210.817.33–7.98(s, d, t)2.76–3.06(t), 1.25–1.56(m), 0.98–1.07(t)
Me2SnCl(L2)11.057.16–8.05(s, d, t)2.72–2.91(t), 1.59–1.74(m), 0.86–0.91(t)
Me2Sn(L1)210.947.27–8.04(s, d, t)2.59–2.64(t), 1.53–1.67(m), 0.89–0.94(t)