ISRN Nanomaterials

Volume 2013, Article ID 504341, 7 pages

http://dx.doi.org/10.1155/2013/504341

## Optical Absorption in Nano-Structures: Classical and Quantum Models

Department of Electrical and Computer Engineering, Michigan Technological University, Houghton, MI 49931, USA

Received 11 September 2013; Accepted 7 October 2013

Academic Editors: M. R. Ferreira and M. Mirzaei

Copyright © 2013 Anand Kulkarni et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

In the last decade, nano-structured materials have gained a significant interest for applications in solar cells and other optical and opto-electronic devices. Due to carrier confinement, the absorption characteristics in these structures are quite different from the absorption in bulk materials and thin films. Optical absorption coefficients of a silicon nano-wire are obtained based on a semi-classical model where the photon-electron interaction is described by the interaction of an electromagnetic wave with the electrons in the valence band of a semiconductor. The absorption characteristics showed enhanced optical absorption but no resonant peaks. In our modified model, we have identified optically active inter band transitions by performing electronic structure calculations on unit cells of nano-dimensions. The absorption spectrum obtained here shows explicit excitonic processes. This absorption is tunable from the visible region to near UV portion of the solar spectrum. In our previous work on thin films (100 nm) of ITO, we have used classical Drude model to describe free electron absorption. Using the imaginary part of the calculated complex dielectric function, we have plotted the absorption coefficient versus wavelength of the photon and compared with the experimental data showing good agreement between theory and experiment.

#### 1. Introduction

The efficiency of a solar cell is dependent on the optical absorption of the material used to fabricate the solar cell. In bulk crystalline materials and even in thin films, the bulk absorption coefficient is the most important parameter that determines the optical absorption. Classical models such as Drude model or Drude-Lorentz model describe the optical absorption based on the complex dielectric function [1, 2]. This approach works very well for the absorption of photons by the electrons inside a band, for example, conduction band. However, from band to band excitation of electrons, a detailed understanding of the band structure of the material is essential. To calculate band structure in semiconductors, one has to invoke quantum mechanical models using Schrodinger's wave equation [3, 4]. In this paper, we illustrate the applications of classical and quantum models with examples from our past research on indium tin oxide (ITO) thin films [5, 6], silicon quantum dots [7], and silicon nanowires [8]. In nanostructures, excitons play a dominant role [9, 10].

#### 2. Classical Models

##### 2.1. Drude Model

When the energy of incident radiation is less than the band gap energy of a semiconductor (typically 1 eV), free carrier absorption (electrons in the conduction band and holes in the valence band) takes place. The electric fields of the incident photons accelerate the electrons, which in turn are decelerated by collisions with the phonons, the quantized vibrations of the lattice.

Using Maxwell's equations, it is possible to derive an expression for the complex dielectric function [11]:
Here and are the refractive index and extinction coefficient, respectively. is the high-frequency dielectric constant, is the free electron concentration, is the electron charge, is the effective mass, and is the relaxation time. The imaginary part of is obtained from (1) as
Defining plasma frequency, , as
an expression for the extinction coefficient, is obtained from (1), (2), and (3):
where ; if , , at extremely high frequencies, as expected and if and *, *then . If then,

As an example, let us consider an ITO film having cm^{−3}. Assuming , being free electron mass, and (i.e., cm^{2}V^{−1}s^{−1}), the plasma frequency, s^{−1} or s^{−1} is in the infrared region. However, for metals, the plasma frequency can be in the visible or ultraviolet region because of very high free carrier concentration. The absorption coefficient, , is related to the extinction coefficient, , by a simple equation:

It is to be noted that is proportional to and can be controlled from s^{−1} to s^{−1} by changing m^{−3} to m^{−3} [12].

Figure 1 shows a plot of estimated and measured absorption coefficient versus wavelength for an ITO film. As seen in this figure, the calculated plot compares well with the measured data of absorption coefficient for ITO films by Steckl and Mohammed [13]. However, the agreement of the experimental data with the classical Drude theory may deviate because of the following reasons.(1)Drude theory assumes relaxation time, , independent of electron energy.(2)When photon energies are large compared to the electron energies, quantum models are applicable and these results predict a dependence rather than dependence as predicted by the Drude theory [2].

#### 3. Quantum Models

##### 3.1. Bulk Material and Thin Films

To determine band to band absorption in a semiconductor, one solves time dependent Schrödinger equation: where is the unperturbed Hamiltonian of the system and corresponds to electron-photon interaction. Representing the photon by a vector potential in the form of a plane electromagnetic wave, where is the unit polarization vector in the direction of , and is the wave vector of the photon. Using this approach, one solves the transition probability of a transition from state to state given by [4] as

Equation (9) shows clearly that the probability of an electron making a transition from state with energy to a state m with energy is zero unless the photon energy is equal to the difference in energy between the states, thus conserving energy. Also the transition probability is directly proportional to time . is the time independent matrix element for a given transition from state to state .

The total probability of the transition and the transition probability rate (probability per unit volume per unit time) are given by where is the crystal volume and is the Fermi Dirac distribution function. Expressing as a sum of allowed and forbidden transitions, it is possible to reduce the allowed Hamiltonian to . Thus, is given by where is the oscillator strength, a dimensionless quantity defined as

This oscillator strength for a given transition can vary from very low values to 1 depending upon the selection rules. It is significantly higher in direct semiconductors like GaAs. Absorption coefficient, , is defined as the transition rate per unit quantum flux (quantum flux is defined as the number of incident photons per unit time). for direct band gap semiconductor, where is the reduced mass and is the refractive index. Substituting the values for the constants for GaAs, we get Figure 2 shows a plot of versus along with an experimental plot for GaAs. A very good agreement is seen between theory and experiment at low photon energies and the discrepancy between experimental data and theory at high photon energies may be due to free carrier absorption as well.

##### 3.2. Nanostructures

In order to improve the efficiency of a solar cell, one obvious choice is to use multiple band gap devices to enable absorption of maximum number of photons of the solar spectrum. These devices also called “tandem” solar cells are discussed in the literature [14, 15]. Here the complexity of materials used, the compatibility of the adjacent layers, and the manufacturing difficulties lead to very expensive devices for increased efficiency performance.

An alternative way to boost optical absorption is to use nano structure based devices to attain multiple band gaps based on the size of the quantum dots or quantum wells (based on quantum mechanics, the size of the dot or well determines the band gap of the material). Since the nanostructures of silicon result in direct band gap material, the optical absorption is enhanced due to an increase of oscillator strength. We assumed a value of one for the oscillator strength of nanostructured silicon and the reduced mass is taken as half the mass of electron rest mass. The band gap energy is taken as 1.82 eV for a cluster of 18 atoms (a quantum dot of radius 1 nm) [16]. Plugging the numbers in (13), we get an expression for the absorption coefficient for nano structured silicon as
where is the incident photon wavelength in *μ*m. is the refractive index given by Herzberger's formula.

Figure 3 shows a plot of versus based on (16) and Figure 4 shows a plot of versus for nanostructures of bandgap varying from 1.69 eV to 3.65 eV (quantum dot size varies from 2 nm to 7 nm [17, 18]). As seen in Figure 4, the absorption coefficient, quickly increases to cm^{−1} for a quantum dot having eV. Comparing values in bulk silicon (less than 10^{4} cm^{−1}), we observe an order of magnitude enhancement in . Smith et al. have performed time resolved PL measurements on silicon nano-particles (~1 nm) and have reported direct band to band transition with emission in the wavelength range of 400–480 nm supporting our estimated results [19].

These authors also note that polysilane displays strong absorption from 280 to 350 nm to further substantiate our theoretical plots. The decrease of absorption coefficients for low values of wavelength is related to significant increase in refractive index with decreasing wave lengths in bulk silicon which may not be true in silicon nanostructures.

##### 3.3. Revised Band Structures

In order to improve our quantum mechanical model for nanostructures, we performed electronic structure calculations on unit cells of nano dimensions and determined optically active interband transitions. The computations were carried out using a density functional DFT-LDA approach using a parallel binary of the PWScf distribution. Figure 5 shows silicon nanowire unit cell geometries seen along direction. Three nanowire unit cells with a diameter 0.434 nm, 0.816 nm, and 1.075 nm have been designated as Si11, Si22, and Si33 systems. The details of the calculations and computed oscillator strengths for direct transitions can be found in another paper [8]. In summary, silicon nanowires exhibited direct band gaps as observed by several other research groups [20–22]. The energy band structures for these systems are shown in Figure 6. Exhibiting dispersion curves with very small slopes, these curves yield exceptionally high effective masses for electrons and holes (see Table 1). The absorption spectrum of these nanostructures shows explicit excitonic processes and these processes are described in detail below.

#### 4. Excitonic Processes

Because of the confinement of electrons and holes in nanostructures, the photon energy absorbed will result into excitons with significant binding energies (in eV) and appreciable life times (in µs). We have evaluated the dependence of the binding energy () of 1-D exciton on the length of a nanowire. Following the methods outlined in [23, 24], solving a two particle Schrödinger wave equation for an electron-hole system, and using approximate Hamiltonian, , and the wave function, , and a variational method of minimizing the total energy over different values of (a fitting constant of ), the ground state of exciton binding energy is calculated as

The minimum value of corresponds to the effective Bohr radius of the exciton. The binding energies have been plotted on a function of nanowire length in Figure 7. The binding energies monotonically increase as the nanowire is made shorter. This dependence is expected as the strong confinement causes an increase in the effective mass of the charge carriers. The bulk excitonic binding energy is dependent on the reduced mass of the exciton given by where . The typical Bohr radii for the 1D free exciton, , was found to range between 2.5 and 5 nm. The radiative life time, , is related to the oscillator strength and the exciton binding energy () by the relation [25, 26]: where . These nanowires exhibit unusually large exciton life times in the order of a microsecond. The results for a specimen of 10 nm are summarized in Table 1. As seen in this table, gradually increases from Si33 to Si11 due to a decrease of screening potential with a decrease of nearest neighbors. As increases, decreases, decreasing , thus increasing the radiative life time as expected. However, a large oscillator strength (determined by selective rules) may result into a quicker decay as seen is Si11c compared to Si11a and Si11b.

The , absorption coefficients for Si11, Si22, and Si33, are shown in Figure 8. The lowest excitonic peaks for each of the nanowires occur at 5.25 eV (232 nm), 3.7 eV (335 nm), and 2.3 eV (539 nm) in the increasing order of size. The peak absorption coefficients range from m^{−1} for Si11 to m^{−1} for Si33. These values are approximately an order of magnitude higher compared to versus shown in Figure 4, where the excitonic effects are not included. Note that absorption is tunable from visible region to the near UV portion of the solar spectrum. The prominent peaks seen in Si22 wire are less prominent in Si33 wire since the density of states in conduction band of Si33 increases (compared to Si22), thus decreasing the resonance effects. Also the rippled nature of the absorption spectrum is less in Si33 compared to Si22. Thus, the absorption spectra of nanostructures are dominated by the excitonic processes.

#### 5. Conclusions

Drude model gives a fairly good explanation of the optical absorption by free carriers. Though one could describe the excitations of free electrons in the conduction band using quantum mechanics, the advantages are valid when photon energies are significantly higher than electron energies. For band to band transition, the quantum mechanical models depicting the details of the band structures are essential to fully explain the observed absorption spectrum in bulk and thin film materials. This approach is not adequate to explain the optical absorption spectra in nanostructures which show resonant peaks and enhanced absorption. Here electronic structure calculations on unit cells of nano dimensions lead to excitonic processes that have a significant impact on absorption. The versus curves show weak dispersion in nanostructures compared to those of bulk materials resulting in heavier effective masses for both electrons and holes. The binding energies of excitons in nanostructures are a few tenths of eV compared to a few hundredths of eV in bulk materials (0.015 eV in Si). The radiative life times are in microseconds in nanostructures as compared to nanoseconds as observed in direct bandgap semiconductors, for example, GaAs. In nanostructures, only certain transitions from valence band to conduction band dominate indicating large oscillator strengths, a measure on the strength of absorption for a given energy of photon. Hence, optical absorption in nanostructures is a lot more complex phenomena than that in bulk materials or thin films.

#### Acknowledgment

This work was supported by the National Science Foundation under grant CBET-1235750. We also would like to thank Jaspreet Singh and Vidur Parkash for their help with the figures.

#### References

- P. Y. Yu and M. Cardona,
*Fundamentals of Semiconductors*, Springer, New York, NY, USA, 3rd edition, 2001. - E. D. Palik,
*Handbook of Optical Constants of Solids*, Academic Press, New York, NY, USA, 1985. - R. A. Smith,
*Semiconductors*, Cambridge University Press, New York, NY, USA, 2nd edition, 1978. - C. M. Wolfe, N. Holonyak, and G. E. Stillman,
*Physical Properties of Semiconductors*, Pentice Hall, New Jersey, NJ, USA, 1989. - S. A. Knickerbocker and A. K. Kulkarni, “Estimation and verification of the optical properties of indium tin oxide based on the energy band diagram,”
*Journal of Vacuum Science and Technology A*, vol. 14, no. 3, pp. 757–761, 1996. View at Google Scholar · View at Scopus - A. K. Kulkarni and S. A. Knickerbocker, “Estimation and verification of the electrical properties of indium tin oxide based on the energy band diagram,”
*Journal of Vacuum Science and Technology A*, vol. 14, no. 3, pp. 1709–1714, 1996. View at Publisher · View at Google Scholar - J. S. Nayyar and A. Kulkarni, “One aspect of solar cell efficiency: multiple wavelengths photon absorption in nano-silicon structures,” in
*Proceedings of the SPIE Nanoscale Photonic and Cell Technologies for Photovoltaics II*, vol. 7411, August 2009. View at Publisher · View at Google Scholar · View at Scopus - V. Parkash and A. K. Kulkarni, “Optical absorption characteristics of silicon nanowires for photovoltaic applications,”
*IEEE Transactions on Nanotechnology*, vol. 10, no. 6, pp. 1293–1297, 2011. View at Publisher · View at Google Scholar · View at Scopus - T. Takagahara and K. Takeda, “Theory of the quantum confinement effect on excitons in quantum dots of indirect-gap materials,”
*Physical Review B*, vol. 46, no. 23, pp. 15,578–15,581, 1992. View at Publisher · View at Google Scholar · View at Scopus - M. Bruno, M. Palummo, A. Marini, R. Del Sole, and S. Ossicini, “From Si nanowires to porous silicon: the role of excitonic effects,”
*Physical Review Letters*, vol. 98, no. 3, Article ID 036807, 2007. View at Publisher · View at Google Scholar · View at Scopus - P. Y. Yu and M. Cardona,
*Fundamentals of Semiconductors*, Springer, New York, NY, USA, 3rd edition, 2001. - S. A. Knickerbocker,
*Estimation and verification of electrical and optical properties of indium-tin-oxide based on energy band diagrams [Ph.D. thesis]*, Michigan Technological University, Houghton, Mich, USA, 1995. - A. J. Steckl and G. Mohammed, “The effect of ambient atmosphere in the annealing of indium tin oxide films,”
*Journal of Applied Physics*, vol. 51, no. 7, pp. 3890–3895, 1980. View at Publisher · View at Google Scholar · View at Scopus - M. A. Green,
*Third Generation Photovoltaics: Advanced Solar Energy Conversion*, Springer, Berlin, Germany, 2006. - J. Nelson,
*The Physics of Solar Cells*, Imperial College Press, London, UK, 2003. - D. C. Johnson, I. M. Ballard, K. W. J. Barnham et al., “Observation of photon recycling in strain-balanced quantum well solar cells,”
*Applied Physics Letters*, vol. 90, no. 21, Article ID 213505, 2007. View at Publisher · View at Google Scholar · View at Scopus - L. Cuadra, A. Martí, and A. Luque, “Type II broken band heterostructure quantum dot to obtain a material for the intermediate band solar cell,”
*Physica E*, vol. 14, no. 1-2, pp. 162–165, 2002. View at Publisher · View at Google Scholar · View at Scopus - A. Luque and A. Martí, “Ultra-high efficiency solar cells: the path for mass penetration of solar electricity,”
*Electronics Letters*, vol. 44, no. 16, p. 943, 2008. View at Publisher · View at Google Scholar · View at Scopus - A. Smith, Z. H. Yamani, N. Roberts et al., “Observation of strong direct-like oscillator strength in the photoluminescence of Si nanoparticles,”
*Physical Review B*, vol. 72, no. 20, Article ID 205307, 2005. View at Publisher · View at Google Scholar · View at Scopus - E. C. Garnett and P. Yang, “Silicon nanowire radial p-n junction solar cells,”
*Journal of the American Chemical Society*, vol. 130, no. 29, pp. 9224–9225, 2008. View at Publisher · View at Google Scholar · View at Scopus - V. Sivakov, G. Andrä, A. Gawlik et al., “Silicon nanowire-based solar cells on glass: synthesis, optical properties, and cell parameters,”
*Nano Letters*, vol. 9, no. 4, pp. 1549–1554, 2009. View at Publisher · View at Google Scholar · View at Scopus - J. P. Perdew and A. Zunger, “Self-interaction correction to density-functional approximations for many-electron systems,”
*Physical Review B*, vol. 23, no. 10, pp. 5048–5079, 1981. View at Publisher · View at Google Scholar · View at Scopus - Y. Cui, X. Duan, J. Hu, and C. M. Lieber, “Doping and electrical transport in silicon nanowires,”
*Journal of Physical Chemistry B*, vol. 104, no. 22, pp. 5215–5216, 2000. View at Google Scholar · View at Scopus - A. Poruba, J. Springer, L. Mullerova et al., “Temperature dependence of the optical absorption coefficient of microcrystalline silicon,”
*Journal of Non-Crystalline Solids*, vol. 338–340, no. 1, pp. 222–227, 2004. View at Publisher · View at Google Scholar · View at Scopus - P. M. Derlett, T. C. Choy, and A. M. Stoneham, “An investigation of the porous silicon optical absorption power law near the band edge,”
*Journal of Physics*, vol. 7, no. 12, pp. 2507–2523, 1995. View at Publisher · View at Google Scholar · View at Scopus - G. Bastard, E. E. Mendez, L. L. Chang, and L. Esaki, “Exciton binding energy in quantum wells,”
*Physical Review B*, vol. 26, no. 4, pp. 1974–1979, 1982. View at Publisher · View at Google Scholar · View at Scopus