Table of Contents
ISRN Chemical Engineering
Volume 2013 (2013), Article ID 539209, 8 pages
http://dx.doi.org/10.1155/2013/539209
Research Article

Derivation of a Multiparameter Gamma Model for Analyzing the Residence-Time Distribution Function for Nonideal Flow Systems as an Alternative to the Advection-Dispersion Equation

1Department of Civil & Environmental Engineering, Tennessee State University (TSU), Nashville, TN 37209, USA
2United States Geological Survey (USGS), Nashville, TN 37211, USA
3Massie Chair of Excellence, Tennessee State University (TSU), Nashville, TN 37209, USA

Received 27 September 2012; Accepted 19 October 2012

Academic Editors: D. A. Drew and J. A. A. González

Copyright © 2013 Irucka Embry et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A new residence-time distribution (RTD) function has been developed and applied to quantitative dye studies as an alternative to the traditional advection-dispersion equation (AdDE). The new method is based on a jointly combined four-parameter gamma probability density function (PDF). The gamma residence-time distribution (RTD) function and its first and second moments are derived from the individual two-parameter gamma distributions of randomly distributed variables, tracer travel distance, and linear velocity, which are based on their relationship with time. The gamma RTD function was used on a steady-state, nonideal system modeled as a plug-flow reactor (PFR) in the laboratory to validate the effectiveness of the model. The normalized forms of the gamma RTD and the advection-dispersion equation RTD were compared with the normalized tracer RTD. The normalized gamma RTD had a lower mean-absolute deviation (MAD) (0.16) than the normalized form of the advection-dispersion equation (0.26) when compared to the normalized tracer RTD. The gamma RTD function is tied back to the actual physical site due to its randomly distributed variables. The results validate using the gamma RTD as a suitable alternative to the advection-dispersion equation for quantitative tracer studies of non-ideal flow systems.