Table of Contents
ISRN Polymer Science
Volume 2013 (2013), Article ID 590682, 6 pages
Research Article

Study of Dielectric Relaxation Behavior of Liquid Crystal Copolyester Vectra-A by Thermally Stimulated Discharge Current Technique

Department of Physics, Maharishi Markandeshwar University Mullana, Ambala, Haryana 133 207, India

Received 31 January 2013; Accepted 27 February 2013

Academic Editors: A. Hashidzume and A. Mousa

Copyright © 2013 Sapna Kalia et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The dielectric relaxation behavior of thermotropic liquid crystal copolyester of 73% of p-hydroxy-benzoic acid (HBA) and 27% of 2-hydroxy-6-naphthoic acid (HNA) (Vectra-A) at poling temperature 80°C has been studied using thermally stimulated depolarization current (TSDC) technique in the temperature range from 15°C to 250°C. The TSD currents were obtained for different polarizing fields ranging from 3.8 kV/cm to 19.2 kV/cm. TSD current spectra in the temperature range from 15°C to 250°C show three current maxima around 25°C, 110°C, and 220°C. The maxima around 25°C and 110°C correspond to characteristic dipolar relaxations β and α, respectively. The peak around 220°C is due to space charge effects named as δ-relaxation. The various relaxation parameters like activation energy (U), relaxation strength , preexponential factor , the quantity of charge released (Q) and concentration of trap for β- and α-relaxations at polarizing temperature 80°C for different polarizing fields were evaluated using Bucci-Fieschi fit. The linear variation between activation energy and natural logarithm of preexponential factor indicates the presence of compensation effect for dipolar relaxations of Vectra-A under present poling conditions.