Research Article
New Insights into the Chemistry of Oxovanadium(IV) Complexes with N4 Coordinating Ligands
Table 2
Infrared spectral bands of complexes.
| Complex | Bands (cm−1) | (>C=N) | (V–N) |
(V=O)
| of
| of
| ν
4 of
| (N–H) | (N–H) |
| VO(L1)]SO4 | 1614 | 300 | 980 | 1133 | 956 | 602 | 3349 | 3178 | VO(L2)]SO4 | 1612 | 302 | 978
| 1134
| 955
| 604 | 3350 | 3179 | VO(mac1a)]SO4 | 1610 | 302 | 982
| 1133 | 955 | 602 | 3350 | 3179 | VO(mac1b)]SO4 | 1618 | 300 | 982 | 1135 | 956 | 608 | 3350 | 3180 | VO(mac1c)]SO4 | 1610 | 303 | 981 | 1134 | 956 | 604 | 3349 | 3178 | VO(mac1d)]SO4 | 1608 | 303 | 982
| 1134 | 955 | 606 | 3348 | 3179 | VO(mac2a)]SO4 | 1610 | 302 | 984 | 1133 | 956 | 602 | 3348 | 3179 | VO(mac2b)]SO4 | 1612 | 303 | 981 | 1133
| 955
| 604 | 3350 | 3180 | VO(mac2c)]SO4 | 1618 | 302 | 984
| 1135 | 956 | 604 | 3349 | 3178 | VO(mac2d)]SO4 | 1618 | 302 | 980 | 1134 | 955 | 606 | 3349 | 3179 |
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