Table of Contents
ISRN Nanotechnology
Volume 2014 (2014), Article ID 148184, 5 pages
http://dx.doi.org/10.1155/2014/148184
Research Article

Silver Nanoparticles: Green Synthesis, Characterization, and Their Usage in Determination of Mercury Contamination in Seafoods

1Department of Chemistry, Faculty of Science, University of Karachi, Karachi 75270, Pakistan
2Department of Microbiology, Faculty of Science, University of Karachi, Karachi 75270, Pakistan

Received 22 October 2013; Accepted 26 December 2013; Published 4 February 2014

Academic Editors: D. Wang and J. Zhan

Copyright © 2014 Muhammad Ahad Ahmed et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

We demonstrate that silver nanoparticles undergo an interaction with Hg2+ found in traces. The PEG-PVP-stabilized Ag nanoparticles were successfully synthesized via a reduction approach and characterized with surface plasmon resonance UV/Vis spectroscopy. By utilizing the redox reaction between Ag nanoparticles and Hg2+, and the resulted decrease in UV/Vis signal, we develop a colorimetric method for detection of Hg2+ ion. A linear and inversely proportional relationship was found between the absorbance intensity of the Ag nanoparticles and the concentration of Hg2+ ion over the range from 10 ppm to 1 ppm at absorption on 411 nm. The detection limit for Hg2+ ions in homogeneous aqueous solutions is estimated to be 1 ppm. This system shows excellent selectivity for Hg2+. The results found have potential implications in the development of new colorimetric sensors for easy and selective detection and monitoring of mercuric ions in aqueous solutions. The proposed method was successfully applied to quantify the amount of mercury in seafood.