Research Article

Synthesis and Characterization of New Organosoluble and Thermally Stable Poly(thioether-amide)s Bearing Pyridine Subunit in the Main Chain

Table 2

Spectral data of polymers.

PolymerIR ( cm−1) 1H NMR (500 MHz, DMSO-d6): (ppm)

PPY (10)3358, 3072, 2897, 2361, 1698, 1661, 1647, 1445, 1149, and 7334.69 (s, 4H), 7.41 (d, J = 9 Hz, 2H), 7.54–7.57 (m, 3H), 7.68–7.72 (m, 3H), 7.93 (d, J = 8.5 Hz, 2H), 7.99 (d, J = 7.5 Hz, 2H), 8.30 (d, J = 8.5 Hz, 2H), 10.42 (s, 2H), and 10.44 (s, 2H)

PPH (11)3376, 3145, 2983, 2491, 1683, and 11154.37 (s, 4H), 5.98 (m, 1H), 6.15 (m, 2H), 6.97 (m, 1H), 7.28–7.33 (m, 2H), 7.56–7.62 (m, 4H), 7.78–7.82 (m, 3H), 9.95 (dd, J = 1, 8 Hz, 2H), 10.38 (s, 2H), and 10.39 (s, 2H)

PMS (12)3481, 3363, 3224, 2983, 2431, 1698, 1667, 1622, 1595, 1137, and 10453.99 (s, 4H), 6.85–6.87 (m, 2H), 7.08-7.09 (m, 2H), 7.18–7.20 (m, 2H), 7.28–7.31 (m, 2H), 7.61–7.63 (m, 4H), 7.79–7.81 (m, 3H), 9.93 (dd, J = 1, 8 Hz, 2H), 10.37 (s, 2H), and 10.38 (s, 2H)

PPS (13)3366, 3281, 2985, 2433, 1663, 1593, 1138, and 10433.99 (s, 4H), 7.08 (dd, J = 2.5, 7.5 Hz, 2H), 7.41–7.43 (m, 3H), 7.45–7.47 (m, 2H), 7.68 (d, J = 9 Hz, 2H), 7.73 (d, J = 7.5 Hz, 2H), 7.78-7.79 (m, 2H), 7.95–7.98 (m, 2H), 8.86 (s, 1H), 8.92 (s, 1H), 10.92 (s, 2H), and 10.93 (s, 2H)