Unusual Seven Coordination of Oxovanadium(V) Oximato Complex: Synthesis and X-Ray Crystal Structure

Table 2

Selected bond distances (Å) and angles (deg) for [VO(acac)(dametsc)] (1).

V1–S2	2.4899 (9)	O7–V1–O3	177.37 (8)
V1–N4	2.025 (2)	S2–V1–N4	66.44 (6)
V1–N9	1.909 (3)	N4–V1–N9	76.43 (9)
V1–O8	2.105 (2)	N9–V1–O8	37.28 (8)
V1–O6	1.964 (2)	O8–V1–O6	90.82 (9)
V1–O3	2.159 (2)	O6–V1–S2	86.42 (7)
V1–O7	1.586 (2)	O7–V1–O6	94.52 (9)
N4–N5	1.367 (3)	O7–V1–O8	96.59 (9)
C11–N4	1.338 (3)	O7–V1–N9	97.64 (10)
C11–S2	1.721 (3)	O7–V1–N4	98.82 (9)
C12–N (5)	1.300 (3)	O7–V1–S2	95.20 (8)
C13–N (9)	1.292 (4)