Table of Contents
ISRN Polymer Science
Volume 2014, Article ID 873520, 11 pages
http://dx.doi.org/10.1155/2014/873520
Research Article

Removal of Toxic Metal Ions from Water Using Chelating Terpolymer Resin as a Function of Different Concentration Time and pH

1Department of Chemistry, Laxminarayan Institute of Technology, Rashtrasant Tukdoji Maharaj Nagpur University, Nagpur 440 010, India
2Department of Chemistry, Shri Ramdeobaba College of Engineering & Management, Nagpur 440 013, India

Received 22 November 2013; Accepted 28 January 2014; Published 22 May 2014

Academic Editors: C.-Y. Guo, B. Haidar, and M. Sanopoulou

Copyright © 2014 Mangesh S. Dhore et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Terpolymer resin 4-ASAUF was synthesized by the condensation of 4-aminosalicylic acid (4-ASA) and urea (U) with formaldehyde (F) in the presence of 2 N hydrochloric acid. The structure of the resin was characterized by various spectral techniques like infrared (FTIR) and nuclear magnetic resonance (1H and 13C-NMR) spectroscopy. The empirical formula and empirical weight of the resin were determined by elemental analysis. The physiochemical properties of terpolymer resin were determined. The morphological feature of the 4-ASAUF terpolymer resin was studied by scanning electron microscopy (SEM). The chelating ion-exchange property of this copolymer was studied for eight metal ions, namely, Fe3+, Cu2+, Ni2+, Co2+, Hg2+, Zn2+, Cd2+, and Pb2+ ions by using batch equilibrium method. The chelating ion-exchange study was carried out over a wide pH range at different time intervals using different electrolyte of various ionic strengths.