Thermal Decomposition Behavior of Melaminium Benzoate Dihydrate

Table 2

Kinetic parameters of non-isothermal decomposition of MBDH by Flynn-Wall and Friedman methods.

𝛼	Flynn-Wall						Friedman
	Stage I		Stage II		stage III		Stage I		Stage II		Stage III
	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1	𝐸𝑎/kJ mol^−1	ln 𝐴/s^−1
0.1	43.59	11.26	42.13	12.87	95.37	21.48	11.65	3.77	47.79	14.25	30.83	7.56
0.2	45.76	11.93	56.68	16.50	88.32	19.86	19.34	6.46	49.82	14.88	37.36	9.08
0.3	48.62	12.82	70.04	19.87	82.49	18.54	25.13	8.47	43.99	13.35	40.44	9.81
0.4	48.49	12.71	82.44	22.99	78.93	17.71	27.34	9.22	28.57	9.21	42.56	10.33
0.5	48.86	12.76	93.02	25.64	75.54	16.94	27.22	9.16	14.43	3.19	41.78	10.21
0.6	45.91	11.72	62.34	17.55	72.73	16.29	24.75	8.28	14.91	2.42	36.62	9.10
0.7	34.27	7.88	113.93	30.86	69.78	15.64	19.56	6.46	61.59	14.98	23.71	6.29
0.8	12.25	1.19	122.09	32.86	66.45	14.91	12.79	4.09	91.21	22.93	8.92	0.92
0.9	39.89	14.88	130.86	35.00	62.41	14.05	11.02	1.25	79.69	19.94	44.27	8.54