Table of Contents
Journal of Applied Chemistry
Volume 2014, Article ID 484361, 7 pages
http://dx.doi.org/10.1155/2014/484361
Research Article

Electron Donor-Acceptor Interaction of 8-Hydroxyquinoline with Citric Acid in Different Solvents: Spectroscopic Studies

Department of Chemistry, College of Natural Sciences, Jimma University, P.O. Box 378, Jimma, Ethiopia

Received 15 May 2014; Revised 7 July 2014; Accepted 17 July 2014; Published 17 August 2014

Academic Editor: Ming-Jer Lee

Copyright © 2014 Demelash Jado et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Charge transfer complex formation between 8-hydroxyquinoline as the electron donor and citric acid as the electron acceptor has been studied spectrophotometrically in ethanol and methanol solvents at room temperature. Absorption band due to charge transfer complex formation was observed near 320 and 325 nm in ethanol and methanol, respectively. The stoichiometric ratio of the complex has been found 3 : 1 by using Job’s and conductometric titration methods. Benesi-Hildebrand equation has been applied to estimate the formation constant and molecular extinction coefficient. It was found that the value of formation constant was larger in ethanol than in methanol. The physical parameters, ionization potential, and standard free energy change of the formed complex were determined and evaluated in the ethanol and methanol solvents.