Journal of Applied Chemistry

Research Article

Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Cyclohexanone with Isomers of Butanol

Table 2

Experimental values of densities, , ultrasonic speeds, , molar volume, , adiabatic compressibility, , intermolecular free length, , acoustic impedance, , and excess/deviation properties , , , , and for all binary systems with mole fraction, , of cyclohexanone at 308.15 K.


	/(kg m⁻³)	/(m s⁻¹)	/(10⁻⁵ m³ mol⁻¹)	/(10⁻¹⁰ Pa⁻¹)	/(10⁻¹⁰ m)	/(10⁶ kg m⁻² s⁻¹)	/(10⁻⁵ m³ mol⁻¹)	/(10⁻¹⁰ Pa⁻¹)	/(10⁻¹⁰ m)	/(10⁶ kg m⁻² s⁻¹)	/(m s⁻¹)

CH + -butanol
1.0000	939.60	1362.00	7.2100	8.3164	0.6040	1.2797	0.0000	0.0000	0.0000	0.0000	0.00
0.9121	913.91	1331.02	7.2125	8.9952	0.6281	1.2164	0.0977	0.3231	0.0107	−0.0355	−17.55
0.8854	907.20	1322.96	7.2111	9.1843	0.6347	1.2002	0.1252	0.4008	0.0133	−0.0432	−21.54
0.7211	873.62	1283.96	7.1186	10.2048	0.6690	1.1217	0.2105	0.6763	0.0226	−0.0697	−35.45
0.6687	864.85	1274.47	7.0775	10.4903	0.6783	1.1022	0.2261	0.7151	0.0239	−0.0726	−36.94
0.5232	843.20	1252.14	6.9241	11.2327	0.7019	1.0558	0.2302	0.7516	0.0254	−0.0730	−37.05
0.4752	836.65	1246.98	6.8566	11.4565	0.7089	1.0433	0.2147	0.7367	0.0251	−0.0703	−34.88
0.3231	817.59	1230.68	6.6549	12.1558	0.7302	1.0062	0.1776	0.6877	0.0232	−0.0593	−27.95
0.2112	805.99	1220.87	6.4872	12.6087	0.7437	0.9840	0.1311	0.5914	0.0197	−0.0460	−20.68
0.1313	799.91	1215.19	6.3611	12.861	0.7511	0.9720	0.0915	0.4550	0.0150	−0.0328	−14.15
0.0000	796.50	1209.30	6.1275	13.0345	0.7561	0.9632	0.0000	0.0000	0.0000	0.0000	0.00

CH + -butanol
1.0000	939.60	1362.00	7.2100	8.3164	0.6040	1.2797	0.0000	0.0000	0.0000	0.0000	0.00
0.9212	912.29	1329.22	7.2449	9.0394	0.6297	1.2126	0.1060	0.3836	0.0126	−0.0397	−18.02
0.8867	902.08	1316.33	7.2474	9.3357	0.6399	1.1874	0.1397	0.5194	0.0171	−0.0529	−24.46
0.7121	862.17	1263.03	7.2207	10.6512	0.6835	1.0889	0.2705	0.9784	0.0316	−0.0907	−45.07
0.6786	856.20	1254.83	7.2042	10.8709	0.6905	1.0744	0.2843	1.0245	0.0331	−0.0935	−47.00
0.5123	831.56	1221.77	7.0717	11.8365	0.7205	1.0160	0.3018	1.0967	0.0354	−0.0941	−48.93
0.4688	826.13	1215.26	7.0273	12.0569	0.7272	1.0040	0.2967	1.0794	0.0349	−0.0909	−47.29
0.3121	809.26	1196.19	6.8217	12.7651	0.7483	0.9680	0.2325	0.9202	0.0299	−0.0724	−37.03
0.2797	806.31	1193.09	6.7723	12.8921	0.7520	0.9620	0.2124	0.8684	0.0282	−0.0672	−34.06
0.1112	795.03	1180.57	6.5053	13.4011	0.7667	0.9386	0.0974	0.4604	0.0149	−0.0320	−15.04
0.0000	793.20	1174.80	6.3075	13.5292	0.7703	0.9319	0.0000	0.0000	0.0000	0.0000	0.00

CH + -butanol
1.0000	939.60	1362.00	7.2100	8.3164	0.6040	1.2797	0.0000	0.0000	0.0000	0.0000	0.00
0.9221	908.29	1312.68	7.3361	9.2340	0.6364	1.1923	0.1562	0.4969	0.0150	−0.0527	−27.81
0.8895	896.42	1294.40	7.3779	9.6141	0.6494	1.1603	0.2106	0.6834	0.0207	−0.0702	−37.10
0.7012	840.30	1210.44	7.5179	11.7001	0.7164	1.0171	0.4235	1.5137	0.0457	−0.1296	−69.09
0.6814	835.51	1203.37	7.5205	11.9041	0.7226	1.0054	0.4337	1.5721	0.0475	−0.1325	−70.69
0.5112	801.79	1152.77	7.4950	13.4939	0.7693	0.9243	0.4741	1.8707	0.0562	−0.1378	−74.32
0.4777	796.61	1144.65	7.4783	13.7669	0.7771	0.9118	0.4703	1.8823	0.0566	−0.1354	−73.19
0.3321	779.12	1115.24	7.3616	14.7714	0.8049	0.8689	0.4099	1.7360	0.0519	−0.1135	−62.41
0.2635	773.60	1104.59	7.2878	15.1275	0.8146	0.8545	0.3627	1.5506	0.0463	−0.0973	−54.13
0.1323	767.78	1090.36	7.0894	15.5581	0.8261	0.8372	0.2150	0.9556	0.0285	−0.0562	−32.15
0.0000	768.40	1086.00	6.8232	15.5954	0.8271	0.8345	0.0000	0.0000	0.0000	0.0000	0.00