Table of Contents
Journal of Applied Chemistry
Volume 2017, Article ID 7351263, 10 pages
Research Article

A Simple Incorporation Route of Tris(8-hydroxyquinoline)aluminum(III) into Transparent Mesoporous Silica Films and Their Photofunctions

1Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940–2188, Japan
2National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563–8577, Japan

Correspondence should be addressed to Motohiro Tagaya;

Received 21 April 2017; Accepted 28 June 2017; Published 14 August 2017

Academic Editor: Weihua Li

Copyright © 2017 Motohiro Tagaya et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The molecular aggregation states of tris(8-hydroxyquinoline)aluminum(III) (Alq) adsorbed in the transparent mesoporous silica (MPS) films with the different pore sizes (3.0 and 5.4 nm) were successfully clarified. The Alq molecules were easily incorporated into the films from the solution without the segregation on the surfaces. The adsorbed amount of Alq was controlled by changing the added amount in the initial solution to resultantly give the transparent and yellow-color films. The photoluminescence spectra significantly revealed that the state of Alq molecules in the mesopore varied depending on the adsorbed amount of Alq as well as the pore size, suggesting the characteristic mobility of the adsorbed Alq molecules in the mesopores as compared with that at the bulk or solution state. Therefore, the guest-guest interactions between Alq molecules as well as the host-guest interactions between Alq and mesopore were elucidated. This finding by the use of the mesoporous film hosts will be utilized for including luminescence species and be applicable for optical devices.