Table of Contents
Journal of Catalysts
Volume 2015 (2015), Article ID 601709, 9 pages
http://dx.doi.org/10.1155/2015/601709
Research Article

Use of CuNi/YSZ and CuNi/SDC Catalysts for the Reverse Water Gas Shift Reaction

1Chemical and Biological Engineering, University of Ottawa, Ottawa, ON, Canada K1N 6N5
2Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, ON, Canada K1N 6N5

Received 6 October 2014; Revised 18 January 2015; Accepted 19 January 2015

Academic Editor: Hicham Idriss

Copyright © 2015 Maxime Lortie and Rima J. Isaifan. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. T. F. Stocker, D. Qin, G.-K. Plattner et al., Climate Change 2013: The Physical Science Basis Working Group I Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, 2013.
  2. W. Wang, S. Wang, X. Ma, and J. Gong, “Recent advances in catalytic hydrogenation of carbon dioxide,” Chemical Society Reviews, vol. 40, no. 7, pp. 3703–3727, 2011. View at Publisher · View at Google Scholar · View at Scopus
  3. P. Vibhatavata, J.-M. Borgard, M. Tabarant, D. Bianchi, and C. Mansilla, “Chemical recycling of carbon dioxide emissions from a cement plant into dimethyl ether, a case study of an integrated process in France using a Reverse Water Gas Shift (RWGS) step,” International Journal of Hydrogen Energy, vol. 38, no. 15, pp. 6397–6405, 2013. View at Publisher · View at Google Scholar · View at Scopus
  4. S. S. Kim, K. H. Park, and S. C. Hong, “A study of the selectivity of the reverse water-gas-shift reaction over Pt/TiO2 catalysts,” Fuel Processing Technology, vol. 108, pp. 47–54, 2013. View at Publisher · View at Google Scholar · View at Scopus
  5. S. S. Kim, H. H. Lee, and S. C. Hong, “A study on the effect of support's reducibility on the reverse water-gas shift reaction over Pt catalysts,” Applied Catalysis A: General, vol. 423-424, pp. 100–107, 2012. View at Publisher · View at Google Scholar · View at Scopus
  6. S. S. Kim, H. H. Lee, and S. C. Hong, “The effect of the morphological characteristics of TiO2 supports on the reverse water-gas shift reaction over Pt/TiO2 catalysts,” Applied Catalysis B: Environmental, vol. 119–120, pp. 100–108, 2012. View at Publisher · View at Google Scholar · View at Scopus
  7. C. Chen, C. Ruan, Y. Zhan, X. Lin, Q. Zheng, and K. Wei, “The significant role of oxygen vacancy in Cu/ZrO2 catalyst for enhancing water-gas-shift performance,” International Journal of Hydrogen Energy, vol. 39, no. 1, pp. 317–324, 2014. View at Publisher · View at Google Scholar · View at Scopus
  8. J. Papavasiliou, G. Avgouropoulos, and T. Ioannides, “Effect of dopants on the performance of CuO-CeO2 catalysts in methanol steam reforming,” Applied Catalysis B: Environmental, vol. 69, no. 3-4, pp. 226–234, 2007. View at Publisher · View at Google Scholar · View at Scopus
  9. F. S. Stone and D. Waller, “Cu-ZnO and Cu-ZnO/Al2O3 catalysts for the reverse water-gas shift reaction. The effect of the Cu/Zn ratio on precursor characteristics and on the activity of the derived catalysts,” Topics in Catalysis, vol. 22, no. 3-4, pp. 305–318, 2003. View at Publisher · View at Google Scholar · View at Scopus
  10. C. S. Chen, J. H. Wu, and T. W. Lai, “Carbon dioxide hydrogenation on Cu nanoparticles,” Journal of Physical Chemistry C, vol. 114, no. 35, pp. 15021–15028, 2010. View at Publisher · View at Google Scholar · View at Scopus
  11. C.-S. Chen, W.-H. Cheng, and S.-S. Lin, “Study of iron-promoted Cu/SiO2 catalyst on high temperature reverse water gas shift reaction,” Applied Catalysis A: General, vol. 257, no. 1, pp. 97–106, 2004. View at Publisher · View at Google Scholar · View at Scopus
  12. C.-S. Chen, W.-H. Cheng, and S.-S. Lin, “Study of reverse water gas shift reaction by TPD, TPR and CO2 hydrogenation over potassium-promoted Cu/SiO2 catalyst,” Applied Catalysis A: General, vol. 238, no. 1, pp. 55–67, 2002. View at Publisher · View at Google Scholar · View at Scopus
  13. C. S. Chen, J. H. Lin, J. H. You, and K. H. Yang, “Effects of potassium on Ni-K/Al2O3 catalysts in the synthesis of carbon nanofibers by catalytic hydrogenation of CO2,” Journal of Physical Chemistry A, vol. 114, no. 11, pp. 3773–3781, 2010. View at Publisher · View at Google Scholar · View at Scopus
  14. Y. Liu and D. Liu, “Study of bimetallic Cu-Ni/γ-Al2O3 catalysts for carbon dioxide hydrogenation,” International Journal of Hydrogen Energy, vol. 24, no. 4, pp. 351–354, 1999. View at Publisher · View at Google Scholar · View at Scopus
  15. M. Ismail, Model Development and Validation of Samaria Doped Ceria (SDC) Based Solid Oxide Fuel Cell Operating with Practical Fuels, Univiersity of Waterloo, 2013.
  16. G. Pekridis, K. Kalimeri, N. Kaklidis et al., “Study of the reverse water gas shift (RWGS) reaction over Pt in a solid oxide fuel cell (SOFC) operating under open and closed-circuit conditions,” Catalysis Today, vol. 127, no. 1–4, pp. 337–346, 2007. View at Publisher · View at Google Scholar · View at Scopus
  17. T. H. Etsell and S. N. Flengas, “The electrical properties of lanthanum oxide-calcium oxide solid electrolytes,” Journal of the Electrochemical Society, vol. 116, no. 6, pp. 771–778, 1969. View at Publisher · View at Google Scholar
  18. C. Zhang, C.-J. Li, G. Zhang et al., “Ionic conductivity and its temperature dependence of atmospheric plasma-sprayed yttria stabilized zirconia electrolyte,” Materials Science and Engineering B: Solid-State Materials for Advanced Technology, vol. 137, no. 1–3, pp. 24–30, 2007. View at Publisher · View at Google Scholar · View at Scopus
  19. W. P. Dow and T. J. Huang, “Effects of oxygen vacancy of yttria-stabilized zirconia support on carbon monoxide oxidation over copper catalyst,” Journal of Catalysis, vol. 147, no. 1, pp. 322–332, 1994. View at Publisher · View at Google Scholar · View at Scopus
  20. W.-P. Dow, Y.-P. Wang, and T.-J. Huang, “Yttria-stabilized zirconia supported copper oxide catalyst. I. Effect of oxygen vacancy of support on copper oxide reduction,” Journal of Catalysis, vol. 160, no. 2, pp. 155–170, 1996. View at Publisher · View at Google Scholar · View at Scopus
  21. G. Avgouropoulos, M. Manzoli, F. Boccuzzi et al., “Catalytic performance and characterization of Au/doped-ceria catalysts for the preferential CO oxidation reaction,” Journal of Catalysis, vol. 256, no. 2, pp. 237–247, 2008. View at Publisher · View at Google Scholar · View at Scopus
  22. H. Yahiro, K. Eguchi, and H. Arai, “Electrical properties and reducibilities of ceria-rare earth oxide systems and their application to solid oxide fuel cell,” Solid State Ionics, vol. 36, no. 1-2, pp. 71–75, 1989. View at Publisher · View at Google Scholar · View at Scopus
  23. R. J. Isaifan, H. A. E. Dole, E. Obeid, L. Lizarraga, E. A. Baranova, and P. Vernoux, “Catalytic CO oxidation over Pt nanoparticles prepared from the polyol reduction method supported on yttria-stabilized zirconia,” The Electrochemical Society, vol. 35, no. 28, pp. 43–57, 2011. View at Google Scholar
  24. M. Lortie, Reverse water gas shift reaction over supported Cu-Ni nanoparticle catalysts, chapter 3 [M.S. thesis], University of Ottawa, 2014.
  25. R. J. Isaifan, S. Ntais, and E. A. Baranova, “Particle size effect on catalytic activity of carbon-supported Pt nanoparticles for complete ethylene oxidation,” Applied Catalysis A: General, vol. 464-465, pp. 87–94, 2013. View at Publisher · View at Google Scholar · View at Scopus
  26. J. Papavasiliou, G. Avgouropoulos, and T. Ioannides, “Effect of dopants on the performance of CuO-CeO2 catalysts in methanol steam reforming,” Applied Catalysis B: Environmental, vol. 69, no. 3-4, pp. 226–234, 2007. View at Publisher · View at Google Scholar · View at Scopus
  27. A. Dauscher, L. Hilaire, F. Le Normand, W. Muller, G. Maire, and A. Vasquez, “Characterization by XPS and XAS of supported Pt/TiO2-CeO2 catalysts,” Surface and Interface Analysis, vol. 16, no. 1–12, pp. 341–346, 1990. View at Publisher · View at Google Scholar · View at Scopus
  28. C. M. Kalamaras, P. Panagiotopoulou, D. I. Kondarides, and A. M. Efstathiou, “Kinetic and mechanistic studies of the water-gas shift reaction on Pt/TiO2 catalyst,” Journal of Catalysis, vol. 264, no. 2, pp. 117–129, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. A. Goguet, F. C. Meunier, D. Tibiletti, J. P. Breen, and R. Burch, “Spectrokinetic investigation of reverse water-gas-shift reaction intermediates over a Pt/CeO2 catalyst,” Journal of Physical Chemistry B, vol. 108, no. 52, pp. 20240–20246, 2004. View at Publisher · View at Google Scholar · View at Scopus
  30. J. B. Peri, “A model for the surface of γ-alumina,” Journal of Physical Chemistry, vol. 69, no. 1, pp. 220–230, 1965. View at Publisher · View at Google Scholar · View at Scopus
  31. D. A. Cadenhead and N. J. Wagner, “Low-temperature hydrogen adsorption on copper-nickel alloys,” The Journal of Physical Chemistry, vol. 72, no. 8, pp. 2775–2781, 1968. View at Publisher · View at Google Scholar · View at Scopus
  32. E.-M. Köck, M. Kogler, T. Bielz, B. Klötzer, and S. Penner, “In situ FT-IR spectroscopic study of CO2 and CO adsorption on Y2O3, ZrO2, and yttria-stabilized ZrO2,” Journal of Physical Chemistry C, vol. 117, no. 34, pp. 17666–17673, 2013. View at Publisher · View at Google Scholar · View at Scopus
  33. G. Finos, S. Collins, G. Blanco et al., “Infrared spectroscopic study of carbon dioxide adsorption on the surface of cerium-gallium mixed oxides,” Catalysis Today, vol. 180, no. 1, pp. 9–18, 2012. View at Publisher · View at Google Scholar · View at Scopus
  34. E. Vesselli, J. Schweicher, A. Bundhoo, A. Frennet, and N. Kruse, “Catalytic CO2 hydrogenation on nickel: novel insight by chemical transient kinetics,” The Journal of Physical Chemistry C, vol. 115, no. 4, pp. 1255–1260, 2011. View at Publisher · View at Google Scholar · View at Scopus
  35. E. Vesselli, M. Rizzi, L. de Rogatis et al., “Hydrogen-assisted transformation of CO2 on nickel: the role of formate and carbon monoxide,” Journal of Physical Chemistry Letters, vol. 1, no. 1, pp. 402–406, 2010. View at Publisher · View at Google Scholar · View at Scopus