Table of Contents
Journal of Ceramics
Volume 2013, Article ID 734015, 6 pages
Research Article

The Lattice Compatibility Theory: Arguments for Recorded I-III-O2 Ternary Oxide Ceramics Instability at Low Temperatures beside Ternary Telluride and Sulphide Ceramics

École Supérieure de Sciences et Techniques de Tunis (ESSTT), Université de Tunis, 63 Rue Sidi Jabeur, 5100 Mahdia, Tunisia

Received 29 October 2012; Revised 13 December 2012; Accepted 15 December 2012

Academic Editor: Joon-Hyung Lee

Copyright © 2013 K. Boubaker. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Some recorded behaviours differences between chalcopyrite ternary oxide ceramics and telluride and sulphides are investigated in the framework of the recently proposed Lattice Compatibility Theory (LCT). Alterations have been evaluated in terms of Urbach tailing and atomic valence shell electrons orbital eigenvalues, which were calculated through several approximations. The aim of the study was mainly an attempt to explain the intriguing problem of difficulties of elaborating chalcopyrite ternary oxide ceramics (I-III-O2) at relatively low temperatures under conditions which allowed crystallization of ternary telluride and sulphides.